Bis{ N 2 , N 6 -bis[(pyridin-3-yl)methyl]pyridine-2,6-dicarboxamide-κ N }bis(methanol-κ O )bis(thiocyanato-κ N )cobalt(II)

In the title compound, [Co(NCS) 2 (C 19 H 17 N 5 O 2 ) 2 (CH 3 OH) 2 ], the Co II atom lies on an inversion center and is coordinated by two isothiocyanate N atoms, two O atoms of methanol molecules and two pyridine N atoms in a slightly distorted octahedral environment. Intermolecular O—H...O and N...

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Bibliographic Details
Published inActa crystallographica. Section E, Structure reports online Vol. 68; no. 6; p. m765
Main Authors Yang, Guang-Rui, Ren, Juan, Li, Guo-Ting
Format Journal Article
LanguageEnglish
Published United States International Union of Crystallography 01.06.2012
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Summary:In the title compound, [Co(NCS) 2 (C 19 H 17 N 5 O 2 ) 2 (CH 3 OH) 2 ], the Co II atom lies on an inversion center and is coordinated by two isothiocyanate N atoms, two O atoms of methanol molecules and two pyridine N atoms in a slightly distorted octahedral environment. Intermolecular O—H...O and N—H...N hydrogen bonds join the complex molecules into layers parallel to the bc plane.
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ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536812020326