Evaluation of Photocatalytic Activity and Electrochemical Properties of Hematite Nanoparticles

• Published in: Symmetry (Basel) Vol. 15; no. 6; p. 1139
• Main Authors: Sagadevan, Suresh, Sivasankaran, Ramesh Poonchi, Lett, J. Anita, Fatimah, Is, Weldegebrieal, Getu Kassegn, Léonard, Estelle, Le, Minh-Vien, Soga, Tetsuo
• Format: Journal Article
• Language: English
• Published: Basel MDPI AG 01.05.2023; MDPI
• Subjects: Analysis; Asymmetry; Carrier transport; Catalytic activity; Chemical properties; Chemical Sciences; Current carriers; Degradation; Diffuse reflectance spectroscopy; Electrochemical analysis; Electrodes; Electromagnetic absorption; Ethanol; Ferric oxide; Fourier transforms; Functional groups; Hematite; Heterojunctions; hydrothermal synthesis; Infrared spectroscopy; Metal oxides; Methylene blue; Morphology; Nanomaterials; Nanoparticles; Optical properties; Oxidation; Photocatalysis; photocatalytic activity; Pollutants; X ray powder diffraction; United States > US
• ISSN: 2073-8994; 2073-8994
• DOI: 10.3390/sym15061139

The symmetric nano morphologies, asymmetric electronic structures, and as well as the heterojunctions of the developed photocatalytic systems perform a vital role in promoting light absorption, separation of electron and hole pairs and charge carrier transport to the surface when exposed to near-infrared (NIR) light. In this present work, we synthesized hematite (α-Fe2O3) nanoparticles (NPs) by a facile hydrothermal method and studied their structural, optical, and photocatalytic properties. Powder X-ray diffraction (XRD) confirmed the rhombohedral phase of the α-Fe2O3 NPs, and Fourier transform infrared spectroscopy (FT-IR) was used to investigate symmetric and asymmetric stretching vibrations of the functional groups on the surface of the catalysts. The optical bandgap energy was estimated to be 2.25 eV using UV-Vis diffuse reflectance spectroscopy (UV-Vis DRS) and scanning electron microscopy (SEM) images indicated sphere like morphology. The oxidation and reduction properties of α-Fe2O3 NPs were analyzed by cyclic voltammetry (CV). The α-Fe2O3 NPs were utilized for the degradation of methylene blue (MB) dye under natural sunlight. The experimental results demonstrate that the degradation efficiency was achieved at 33% in 2 h, and the pseudo-first-order rate constant was calculated to be 0.0033 min−1.