Crystal structure of (perchlorato-κ O )(1,4,7,10-tetra-aza-cyclo-dodecane-κ 4 N )copper(II) perchlorate

The crystal structure of the title salt, [Cu(ClO )(C H N )]ClO , is reported. The Cu ion exhibits a square-pyramidal geometry and is coordinated by the four N atoms of the neutral 1,4,7,10-tetra-aza-cyclo-dodecane (cyclen) ligand and an O atom from one perchlorate anion, with the second perchlorate...

Full description

Saved in:
Bibliographic Details
Published inActa crystallographica. Section E, Crystallographic communications Vol. 73; no. Pt 1; pp. 31 - 34
Main Authors Gray, Jessica L, Gerlach, Deidra L, Papish, Elizabeth T
Format Journal Article
LanguageEnglish
Published England International Union of Crystallography 01.01.2017
Subjects
copper(II)
crystal structure
cyclen
perchlorate
Research Communications
crystal structure
copper(II)
cyclen
perchlorate
Online AccessGet full text

Cover

More Information
Summary:The crystal structure of the title salt, [Cu(ClO )(C H N )]ClO , is reported. The Cu ion exhibits a square-pyramidal geometry and is coordinated by the four N atoms of the neutral 1,4,7,10-tetra-aza-cyclo-dodecane (cyclen) ligand and an O atom from one perchlorate anion, with the second perchlorate ion hydrogen-bonded to one of the amine N atoms of the cyclen ligand. Additional N-H⋯O hydrogen bonds between the amine H atoms and the coordinating and non-coordinating perchlorate groups create a three-dimensional network structure. Crystals were grown from a concentrated methanol solution at ambient temperature, resulting in no co-crystallization of solvent.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:2056-9890
2056-9890
DOI:10.1107/S2056989016019563