Efficient Adsorption and Catalytic Reduction of Phenol Red Dye by Glutaraldehyde Cross-Linked Chitosan and Its Ag-Loaded Catalysts: Materials Synthesis, Characterization and Application

• Published in: Clean technologies Vol. 5; no. 2; pp. 466 - 483
• Main Authors: Siciliano, Chiara Concetta, Dinh, Van Minh, Canu, Paolo, Mikkola, Jyri-Pekka, Khokarale, Santosh Govind
• Format: Journal Article
• Language: English
• Published: Basel MDPI AG 01.06.2023
• Subjects: Adsorption; Ag/chitosan catalyst; Aqueous solutions; catalyst reusability; Catalysts; Catalytic activity; catalytic reduction; Chemical properties; Chemical reduction; Chemical synthesis; Chitosan; cross-linked chitosan; Crosslinking; Dyes; Emission analysis; Fourier transforms; Glutaraldehyde; Inductively coupled plasma; Industrial wastes; Industrial wastewater; Industrial wastewater treatment; Infrared analysis; Infrared spectroscopy; Metal concentrations; Metal oxides; Observations; Optical emission spectroscopy; Oxidation-reduction reaction; pH effects; phenol red dye; Phenols; Reducing agents; Scanning electron microscopy; Silver; Spectrometry; Spectrophotometry; Wastewater treatment; X-ray diffraction; Germany; United States > US
• ISSN: 2571-8797; 2571-8797
• DOI: 10.3390/cleantechnol5020024

In this study, glutaraldehyde cross-linked chitosan support, as well as the catalysts obtained after loading Ag metal (Ag/Chitosan), were synthesised and applied for adsorption and reduction of phenol red dye in an aqueous solution. The Ag/chitosan catalysts were characterised by X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR) and inductively coupled plasma-optical emission spectrometry (ICP-OES) analysis techniques. The catalytic reduction and adsorption performance of phenol red dye with Ag/chitosan and cross-linked chitosan, respectively, was performed at ambient reaction conditions. The reduction of dye was carried out using sodium borohydride (NaBH4) as the reducing agent, while the progress of adsorption and reduction study was monitored with ultraviolet-visible (UV-vis) spectrophotometry technique. The reduction of the phenol red dye varied with the amount of catalyst, the concentration of NaBH4, Ag metal loading, reaction temperature, phenol red dye concentration and initial pH of the dye solution. The dye solution with a nearly-neutral pH (6.4) allowed efficient adsorption of the dye, while acidic (pH = 4) and alkaline (pH = 8, 11, 13.8) solutions showed incomplete or no adsorption of dye. The reusability of the Ag/chitosan catalyst was applied for the complete reduction of the dye, where no significant loss of catalytic activity was observed. Hence, the applicability of cross-linked chitosan and Ag/catalyst was thus proven for both adsorption and reduction of phenol red dye in an aqueous solution and can be applied for industrial wastewater treatment.