Developing Remote Metal Binding Sites in Heteropolymolybdates

Anderson‐type polyoxomolybdates [MMo6O18{(OCH2)3CNH2}2]3− (M = MnIII, FeIII) were prepared and structurally characterized. The tris(alkoxo) ligands are bound to the central heteroatom via their oxygen atoms. The corresponding compounds with M = NiII or ZnII are not accessible since these cations hav...

Full description

Saved in:
Bibliographic Details
Published inEuropean journal of inorganic chemistry Vol. 2003; no. 13; pp. 2406 - 2412
Main Authors Marcoux, Pierre R., Hasenknopf, Bernold, Vaissermann, Jacqueline, Gouzerh, Pierre
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 01.07.2003
WILEY‐VCH Verlag
Wiley-VCH Verlag
Subjects
Chemical Sciences
Coordination chemistry
Material chemistry
Molybdenum
N ligands
Polyoxometalates
Polyoxometalates
N ligands
Molybdenum
Coordination chemistry
Online AccessGet full text

Cover

More Information
Summary:Anderson‐type polyoxomolybdates [MMo6O18{(OCH2)3CNH2}2]3− (M = MnIII, FeIII) were prepared and structurally characterized. The tris(alkoxo) ligands are bound to the central heteroatom via their oxygen atoms. The corresponding compounds with M = NiII or ZnII are not accessible since these cations have a preference for the amino functionality. The pendant amino groups of the manganese‐containing derivative react with pyridinecarbaldehydes to give the corresponding imines. This provides new mono‐ and bidentate binding sites for metal cations. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)
Bibliography:ark:/67375/WNG-QNR59ZNJ-6
istex:4B2A81E9E188517E9EDD2260ADC43DF1F9599178
ArticleID:EJIC200200677
ISSN:1434-1948
1099-0682
DOI:10.1002/ejic.200200677