Bis-(2-methyl-1H-imidazole-κN)bis[2-(naphthalen-2-yl)acetato-κO]copper(II)

In the crystal structure of the title compound, [Cu(C(12)H(9)O(2))(2)(C(4)H(6)N(2))(2)], the Cu(II) cations are square-planar coordinated by two 1-naphthyl-acetate anions and two 2-methyl-imidazole ligands into discrete complexes that are located on centres of inversion. These complexes are linked i...

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Published inActa crystallographica. Section E, Structure reports online Vol. 67; no. Pt 12; p. m1772
Main Authors Yin, Fu-Jun, Han, Li-Jun, Yang, Shu-Ping, Xu, Xing You
Format Journal Article
LanguageEnglish
Published United States International Union of Crystallography 01.12.2011
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Summary:In the crystal structure of the title compound, [Cu(C(12)H(9)O(2))(2)(C(4)H(6)N(2))(2)], the Cu(II) cations are square-planar coordinated by two 1-naphthyl-acetate anions and two 2-methyl-imidazole ligands into discrete complexes that are located on centres of inversion. These complexes are linked into chains parallel to [010] by inter-molecular N-H⋯O hydrogen bonding between the N-H H atom of the 2-methyl-imidazole ligands and the carboxyl-ate O atoms that are not involved in metal coordination.
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ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536811047969