1-[(6-Chloro-pyridin-3-yl)meth-yl]imidazolidin-2-iminium chloride

The title compound, C(9)H(12)ClN(4) (+)·Cl(-), is a natural metabolic product of imidacloprid [systematic name: (E)-1-(6-chloro-3-pyridyl-meth-yl)-N-nitro-imidazolidin-2-yl-idene-amine] and was obtained by the reduction of the latter using Fe in HCl. The dihedral angle between the pyridine and imida...

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Published inActa crystallographica. Section E, Structure reports online Vol. 68; no. Pt 1; p. o147
Main Authors Kant, Rajni, Gupta, Vivek K, Kapoor, Kamini, Deshmukh, Madhukar B, Shripanavar, Chetan S
Format Journal Article
LanguageEnglish
Published United States International Union of Crystallography 01.01.2012
Subjects
Organic Papers
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Summary:The title compound, C(9)H(12)ClN(4) (+)·Cl(-), is a natural metabolic product of imidacloprid [systematic name: (E)-1-(6-chloro-3-pyridyl-meth-yl)-N-nitro-imidazolidin-2-yl-idene-amine] and was obtained by the reduction of the latter using Fe in HCl. The dihedral angle between the pyridine and imidazole rings is 62.09 (12)°. The crystal structure is stabilized by N-H⋯Cl and C-H⋯Cl inter-actions involving the chloride anion. The pyridine N and the chloride atoms are not involved in inter-molecular inter-actions.
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ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536811053487