(Benzonitrile-κN)chlorido[hydrido-tris(pyrazol-1-yl-κN)borato](triphenyl-phosphine-κP)ruthenium(II) ethanol solvate

The reaction of [Ru(C(9)H(10)BN(6))Cl(C(18)H(15)P)(2)] with benzo-nitrile leads to crystals of the title compound, [Ru(C(9)H(10)BN(6))Cl(C(18)H(15)P)(C(7)H(5)N)]·C(2)H(5)OH. In the crystal structure, the environment about the ruthenium metal center corresponds to a slightly distorted octa-hedron wit...

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Published inActa crystallographica. Section E, Structure reports online Vol. 65; no. Pt 4; p. m438
Main Authors Tong, Hung-Chun, Hung, Yu-Chen, Wang, Po-Yo, Lin, Chia-Her, Lo, Yih-Hsing
Format Journal Article
LanguageEnglish
Published United States International Union of Crystallography 25.03.2009
Subjects
Metal-Organic Papers
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Summary:The reaction of [Ru(C(9)H(10)BN(6))Cl(C(18)H(15)P)(2)] with benzo-nitrile leads to crystals of the title compound, [Ru(C(9)H(10)BN(6))Cl(C(18)H(15)P)(C(7)H(5)N)]·C(2)H(5)OH. In the crystal structure, the environment about the ruthenium metal center corresponds to a slightly distorted octa-hedron with an average N-Ru-N bite angle of the Tp ligand of 86.6 (2)°.
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ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536809010265