Evaluation of the pyrolytic and kinetic characteristics of Enteromorpha prolifera as a source of renewable bio-fuel from the Yellow Sea of China

• Published in: Chemical engineering research & design Vol. 88; no. 5; pp. 647 - 652
• Main Authors: Li, Demao, Chen, Limei, Zhao, Jinsheng, Zhang, Xiaowen, Wang, Qingyin, Wang, Hongxia, Ye, Naihao
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier B.V 01.05.2010; Elsevier
• Subjects: Activation energy; Applied sciences; Chemical engineering; Chemical engineers; Decomposition; Enteromorpha prolifera; Exact sciences and technology; Heating rate; Kinetics; Pyrolysis; Reaction kinetics; Weight loss; INW, Huanghai Sea; China, People's Rep; Pyrolysis; Enteromorpha prolifera; Kinetics; Reaction order; Heating rate; Fuel; Devolatilization; Thermodynamic properties; Dehydration; Activation energy
• ISSN: 0263-8762
• DOI: 10.1016/j.cherd.2009.10.011

The pyrolytic and kinetic characteristics of Enteromorpha prolifera from the Yellow Sea were evaluated at heating rates of 10, 20 and 50 °C min −1 , respectively. The results indicated that three stages appeared during pyrolysis; dehydration, primary devolatilization and residual decomposition. Differences in the heating rates resulted in considerable differences in the pyrolysis of E. prolifera. Specifically, the increase of heating rates resulted in shifting of the initial temperature, peak temperature and the maximum weight loss to a higher value. The average activation energy of E. prolifera was 228.1 kJ mol −1, the pre-exponential factors ranged from 49.93 to 63.29 and the reaction orders ranged from 2.2 to 3.7. In addition, there were kinetic compensation effects between the pre-exponential factors and the activation energy. Finally, the minimum activation energy was obtained when a heating rate of 20 °C min −1 was used.