(Acetyl-acetonato-κO,O')aqua-[2-(2-nitro-phen-oxy)-N'-(2-oxidobenzyl-idene-κO)acetohydrazidato-κO,N']manganese(III)
In the title complex, [Mn(C(15)H(11)N(3)O(5))(C(5)H(7)O(2))(H(2)O)], the Mn(III) ion has a distorted octa-hedral coordination geometry. It is coordinated by a phen-oxy O atom, a hydrazine N atom and a carbonyl O atom of the 2-(2-nitro-phen-oxy)-N'-(2-oxidobenzyl-idene-κO)acetohydrazidate dianio...
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Published in | Acta crystallographica. Section E, Structure reports online Vol. 65; no. Pt 8; p. m986 |
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Format | Journal Article |
Language | English |
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United States
International Union of Crystallography
25.07.2009
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Abstract | In the title complex, [Mn(C(15)H(11)N(3)O(5))(C(5)H(7)O(2))(H(2)O)], the Mn(III) ion has a distorted octa-hedral coordination geometry. It is coordinated by a phen-oxy O atom, a hydrazine N atom and a carbonyl O atom of the 2-(2-nitro-phen-oxy)-N'-(2-oxidobenzyl-idene-κO)acetohydrazidate dianion, by two O atoms of the acetyl-acetonate anion and by the O atom of a coordinated water mol-ecule. In the crystal structure, complex mol-ecules are linked into centrosymmetric dimeric units through four inter-molecular O-H⋯O hydrogen bonds involving both H atoms of the coordinated water mol-ecule. |
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AbstractList | In the title complex, [Mn(C(15)H(11)N(3)O(5))(C(5)H(7)O(2))(H(2)O)], the Mn(III) ion has a distorted octa-hedral coordination geometry. It is coordinated by a phen-oxy O atom, a hydrazine N atom and a carbonyl O atom of the 2-(2-nitro-phen-oxy)-N'-(2-oxidobenzyl-idene-κO)acetohydrazidate dianion, by two O atoms of the acetyl-acetonate anion and by the O atom of a coordinated water mol-ecule. In the crystal structure, complex mol-ecules are linked into centrosymmetric dimeric units through four inter-molecular O-H⋯O hydrogen bonds involving both H atoms of the coordinated water mol-ecule. In the title complex, [Mn(C15H11N3O5)(C5H7O2)(H2O)], the MnIII ion has a distorted octahedral coordination geometry. It is coordinated by a phenoxy O atom, a hydrazine N atom and a carbonyl O atom of the 2-(2-nitrophenoxy)-N′-(2-oxidobenzylidene-κO)acetohydrazidate dianion, by two O atoms of the acetylacetonate anion and by the O atom of a coordinated water molecule. In the crystal structure, complex molecules are linked into centrosymmetric dimeric units through four intermolecular O—H...O hydrogen bonds involving both H atoms of the coordinated water molecule. In the title complex, [Mn(C 15 H 11 N 3 O 5 )(C 5 H 7 O 2 )(H 2 O)], the Mn III ion has a distorted octahedral coordination geometry. It is coordinated by a phenoxy O atom, a hydrazine N atom and a carbonyl O atom of the 2-(2-nitrophenoxy)- N ′-(2-oxidobenzylidene-κ O )acetohydrazidate dianion, by two O atoms of the acetylacetonate anion and by the O atom of a coordinated water molecule. In the crystal structure, complex molecules are linked into centrosymmetric dimeric units through four intermolecular O—H⋯O hydrogen bonds involving both H atoms of the coordinated water molecule. |
Author | Xiao, Zi-Jing |
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Snippet | In the title complex, [Mn(C(15)H(11)N(3)O(5))(C(5)H(7)O(2))(H(2)O)], the Mn(III) ion has a distorted octa-hedral coordination geometry. It is coordinated by a... In the title complex, [Mn(C 15 H 11 N 3 O 5 )(C 5 H 7 O 2 )(H 2 O)], the Mn III ion has a distorted octahedral coordination geometry. It is coordinated by a... In the title complex, [Mn(C15H11N3O5)(C5H7O2)(H2O)], the MnIII ion has a distorted octahedral coordination geometry. It is coordinated by a phenoxy O atom, a... |
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Title | (Acetyl-acetonato-κO,O')aqua-[2-(2-nitro-phen-oxy)-N'-(2-oxidobenzyl-idene-κO)acetohydrazidato-κO,N']manganese(III) |
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