(Acetyl-acetonato-κO,O')aqua-[2-(2-nitro-phen-oxy)-N'-(2-oxidobenzyl-idene-κO)acetohydrazidato-κO,N']manganese(III)

In the title complex, [Mn(C(15)H(11)N(3)O(5))(C(5)H(7)O(2))(H(2)O)], the Mn(III) ion has a distorted octa-hedral coordination geometry. It is coordinated by a phen-oxy O atom, a hydrazine N atom and a carbonyl O atom of the 2-(2-nitro-phen-oxy)-N'-(2-oxidobenzyl-idene-κO)acetohydrazidate dianio...

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Published inActa crystallographica. Section E, Structure reports online Vol. 65; no. Pt 8; p. m986
Main Author Xiao, Zi-Jing
Format Journal Article
LanguageEnglish
Published United States International Union of Crystallography 25.07.2009
Subjects
Metal-Organic Papers
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Summary:In the title complex, [Mn(C(15)H(11)N(3)O(5))(C(5)H(7)O(2))(H(2)O)], the Mn(III) ion has a distorted octa-hedral coordination geometry. It is coordinated by a phen-oxy O atom, a hydrazine N atom and a carbonyl O atom of the 2-(2-nitro-phen-oxy)-N'-(2-oxidobenzyl-idene-κO)acetohydrazidate dianion, by two O atoms of the acetyl-acetonate anion and by the O atom of a coordinated water mol-ecule. In the crystal structure, complex mol-ecules are linked into centrosymmetric dimeric units through four inter-molecular O-H⋯O hydrogen bonds involving both H atoms of the coordinated water mol-ecule.
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ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536809028177