Visible Light-Mediated Metal-Free Synthesis of Vinyl Sulfones from Aryl Sulfinates

Visible light and eosin Y catalyze the synthesis of vinyl sulfones from aryl sulfinates and alkenes by a photoredox process. The reaction scope is broad in aryl sulfinates and alkenes and the general and simple procedure provides a metal‐free alternative for the synthesis of synthetically valuable v...

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Bibliographic Details
Published inAdvanced synthesis & catalysis Vol. 357; no. 9; pp. 2050 - 2054
Main Authors Meyer, Andreas Uwe, Jäger, Stefanie, Prasad Hari, Durga, König, Burkhard
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 15.06.2015
WILEY‐VCH Verlag
Wiley
Subjects
Alkenes
Aromatic compounds
aryl sulfinates
Catalysis
Chemistry
Chemistry, Applied
Chemistry, Organic
metal-free conditions
photocatalysis
Physical Sciences
Science & Technology
Sulfones
Synthesis
vinyl sulfones
visible light
ASYMMETRIC-SYNTHESIS
ACIDS
(E)-ALKENYL SULFONES
visible light
C-H FUNCTIONALIZATION
ALKYNES
AEROBIC OXYSULFONYLATION
PHOTOREDOX CATALYSIS
ALKENES
metal-free conditions
PHOSPHONATES
vinyl sulfones
CYSTEINE PROTEASE INHIBITORS
aryl sulfinates
photocatalysis
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Summary:Visible light and eosin Y catalyze the synthesis of vinyl sulfones from aryl sulfinates and alkenes by a photoredox process. The reaction scope is broad in aryl sulfinates and alkenes and the general and simple procedure provides a metal‐free alternative for the synthesis of synthetically valuable vinyl sulfones.
Bibliography:istex:44ADB605B5D7D440C1722871A4C6B07E3F9CA059
ark:/67375/WNG-ZPC029M4-Z
ArticleID:ADSC201500142
German Science Foundation (DFG) - No. GRK 1626, Chemical Photocatalysis
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1615-4150
1615-4169
DOI:10.1002/adsc.201500142