Energetic balance in an ultrasonic reactor using focused or flat high frequency transducers

• Published in: Ultrasonics sonochemistry Vol. 14; no. 6; pp. 739 - 749
• Main Authors: Hallez, L., Touyeras, F., Hihn, J.Y., Klima, J.
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier B.V 01.09.2007; Elsevier
• Subjects: Calorimetry; Chemistry; Exact sciences and technology; General and physical chemistry; HIFU; Physical chemistry of induced reactions (with radiations, particles and ultrasonics); Polymer film irradiation; Sonochemistry; Ultrasonic chemistry; HIFU; Calorimetry; Sonochemistry; Polymer film irradiation; Film; Polymer; High frequency; Reactor; Ultrasound
• ISSN: 1350-4177; 1873-2828
• DOI: 10.1016/j.ultsonch.2006.12.012

In order to undertake irradiation of polymer blocks or films by ultrasound, this paper deals with the measurements of ultrasonic power and its distribution within the cell by several methods. The electric power measured at the transducer input is compared to the ultrasonic power input to the cell evaluated by calorimetry and radiation force measurement for different generator settings. Results obtained in the specific case of new transducer types (composites and focused composites i.e., HIFU: high intensity focused ultrasound) provide an opportunity to conduct a discussion about measurement methods. It has thus been confirmed that these measurement techniques can be applied to HIFU transducers. For all cases, results underlined the fact that measurement of radiation pressure for power evaluation is more adapted to low powers (<15 W) and that measurement by calorimetry is a valid technique for global energy measurements. Composites and monocomponent transducers were compared and it appears that the presence of an adaptation glass plate reduces the efficiency of the monocomponent transducers. The distribution of ultrasonic intensity is qualitatively depicted by sono-chemiluminescence of luminol. Finally, the quantity of energy absorbed by samples placed in the sound field is determined and the temperature distribution monitored as a function of wall distance. This energetic balance allows us to understand the global behaviour of all experimental set-ups made up of a generator–transducer–liquid and sample.