Microstructure, mechanical properties and low temperature degradation resistance of 2Y-TZP ceramic materials derived from nanopowders prepared by laser vaporization

• Published in: Journal of the European Ceramic Society Vol. 35; no. 9; pp. 2685 - 2691
• Main Authors: Smirnov, Anton, Kurland, Heinz-Dieter, Grabow, Janet, Müller, Frank A., Bartolomé, José F.
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 01.09.2015
• Subjects: Aging; Laser vaporization; Low temperature degradation; Mechanical properties; Phase transformation; Low temperature degradation; Aging; Mechanical properties; Laser vaporization; Phase transformation
• ISSN: 0955-2219; 1873-619X
• DOI: 10.1016/j.jeurceramsoc.2015.03.006

Starting from commercially available powders of tetragonal zirconia polycrystals (TZP) doped with 3mol% yttria (Tosoh grade TZ-3YS-E) and yttria-free monoclinic zirconia (Tosoh grade TZ-0) powders with an overall Y2O3 content of 2mol% (2Y/TZP) were fabricated by CO2 laser vaporization (LAVA) and wet mixing, respectively. The obtained powders were compacted by spark plasma sintering. The influence of the Y3+ distribution on the mechanical properties and on the low temperature degradation (LTD) of the obtained ceramics was investigated. 2Y/TZP ceramics sintered from LAVA nanoparticles showed significantly enhanced mechanical properties and improved LTD resistance due to the homogeneous yttria and grain size distributions in the ceramic structure. For the first time, the present research has demonstrated the effectiveness and reproducibility of the LAVA process for the preparation of tailored zirconia nanopowders enabling microstructural homogeneity and therefore optimized mechanical properties and degradation resistance of Y-TZP ceramics.