Synthesis of Substituted Naphtho‐Ferrocenes via a Gold(I)‐Catalyzed Intramolecular 6‐endo‐Dig Cyclization

A novel series of naphtho‐ferrocene derivatives were synthesized in high yields by an efficient gold‐catalyzed intramolecular 6‐endo‐dig cyclization strategy. The salient features of this reaction include easy operation, broad substrate scope, high yields, mild conditions and it works well in wet so...

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Bibliographic Details
Published inChinese journal of chemistry Vol. 35; no. 6; pp. 849 - 852
Main Authors Zhang, Pei‐Chao, Wang, Yidong, Qian, Deyun, Li, Wenbo, Zhang, Junliang
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag GmbH & Co. KGaA 01.06.2017
Wiley
Wiley Subscription Services, Inc
Subjects
Air temperature
Chemical synthesis
Chemistry
Chemistry, Multidisciplinary
cyclization
Derivatives
Ferrocenes
Gold
gold(I)‐catalysis
hydroarylation
naphtho‐ferrocenes
PAHs‐metallocenes
Physical Sciences
Science & Technology
Temperature effects
gold(I)-catalysis
ENANTIOSELECTIVE SYNTHESIS
PLANAR CHIRAL FERROCENES
cyclization
DIASTEREO
PHENANTHRENES
HETEROARENES
FULLERENE
naphtho-ferrocenes
CYCLOISOMERIZATION
hydroarylation
EFFICIENT
PAHs-metallocenes
AMIDES
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Summary:A novel series of naphtho‐ferrocene derivatives were synthesized in high yields by an efficient gold‐catalyzed intramolecular 6‐endo‐dig cyclization strategy. The salient features of this reaction include easy operation, broad substrate scope, high yields, mild conditions and it works well in wet solvent under air at room temperature. A novel series of naphtho‐ferrocene derivatives were synthesized by a classical and efficient gold‐catalyzed intramolecular cyclization strategy. This reaction is easy to handle, with broad scope and in quantitative yield, and it works well in wet solvent under air.
ISSN:1001-604X
1614-7065
DOI:10.1002/cjoc.201600886