Highly selective olefin-assisted palladium-catalyzed oxidative carbocyclization via remote olefin insertion

A highly selective olefin-assisted palladium-catalyzed oxidative carbocyclization via remote olefin insertion to afford cyclohexenes has been developed. It was shown that the assisting olefin moiety was indispensable for the formation of the cyclohexene product. Furthermore, preliminary studies on c...

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Bibliographic Details
Published inChemical science (Cambridge) Vol. 8; no. 1; pp. 616 - 620
Main Authors Qiu, Youai, Yang, Bin, Zhu, Can, Backvall, Jan-E.
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 01.01.2017
Subjects
Asymmetry
Chemistry
Chemistry, Multidisciplinary
Cyclohexene
Formations
Insertion
Olefins
Organic Chemistry
organisk kemi
Palladium
Physical Sciences
Science & Technology
CARBONYLATION-ALKYNYLATION
CARBON
C BOND FORMATION
MULTISTEP ELECTRON-TRANSFER
ALPHA-ALLYLATION
BORONIC ESTERS
ALLENES
ARYLATING CARBOCYCLIZATION
ENALLENES
H ACTIVATION
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Summary:A highly selective olefin-assisted palladium-catalyzed oxidative carbocyclization via remote olefin insertion to afford cyclohexenes has been developed. It was shown that the assisting olefin moiety was indispensable for the formation of the cyclohexene product. Furthermore, preliminary studies on chiral anion-induced asymmetrical carbocyclization-borylation of enallenes have been carried out.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:2041-6520
2041-6539
2041-6539
DOI:10.1039/c6sc02660e