Synthesis of a water-soluble thiourea-formaldehyde (WTF) resin and its application to immobilize the heavy metal in MSWI fly ash

• Published in: Journal of environmental management Vol. 182; pp. 328 - 334
• Main Authors: Liu, She-Jiang, Guo, Yu-Peng, Yang, Hong-Yang, Wang, Shen, Ding, Hui, Qi, Yun
• Format: Journal Article
• Language: English
• Published: England Elsevier Ltd 01.11.2016; Academic Press Ltd
• Subjects: Chemical synthesis; Coal Ash - chemistry; Fly ash; Formaldehyde - chemistry; Free formaldehyde; Heavy metals; Humans; Incineration; Incineration - methods; Metals, Heavy - chemistry; MSWI fly ash; Municipal solid waste; Refuse Disposal - methods; Resins; Thiourea - chemistry; Water-soluble thiourea-formaldehyde resin; MSWI fly ash; Water-soluble thiourea-formaldehyde resin; Free formaldehyde; Heavy metals
• ISSN: 0301-4797; 1095-8630
• DOI: 10.1016/j.jenvman.2016.07.086

Because of the high concentrations of heavy metals, municipal solid waste incineration (MSWI) fly ash is classified as a hazardous waste, which need to be treated to avoid damaging the environment. A novel water-soluble thiourea-formaldehyde (WTF) resin was synthesized by two step reactions (hydroxymethylation reaction and condensation reaction) in the laboratory. Synthetic conditions, removal of free formaldehyde in the resin and the ability of immobilization heavy metals in the MSWI fly ash were studied. The possible molecular structure of the resin was also discussed by elemental analysis and FTIR spectra. Experimental results showed that the synthesis conditions of WTF resin were the formaldehyde/thiourea (T/F) mole ratio of 2.5:1, hydroxymethylation at pH 7.0–8.0 and 60 °C for 30min, and condensation of at pH 4.5–5.0 and 80 °C. In addition, the end point of condensation reaction was measured by turbidity point method. The result of elemental analysis and FTIR spectra indicated that thiourea functional group in the WTF resin chelated the heavy metal ions. Melamine can efficiently reduce the free formaldehyde content in the resin from 8.5% to 2%. The leaching test showed that the immobilization rates of Cr, Pb and Cd were 96.5%, 92.0% and 85.8%, respectively. Leaching concentrations of Cr, Pb and Cd in the treated fly ash were decreased to 0.08 mg/L, 2.44 mg/L and 0.23 mg/L, respectively. The MSWI fly ash treated by WTF resin has no harm to the environment. [Display omitted] •A novel way for synthesizing water-soluble thiourea-formaldehyde resin was proposed.•The resin decreased effectively the leaching concentrations of Cr, Pb and Cd.•Melamine can effectively decrease the content of free formaldehyde in the resin.•The structure was characterized by elemental analysis and FTIR spectra.