Preparation of Polymer-Based Nano-Assembled Particles with Fe3O4 in the Core

• Published in: Polymers Vol. 15; no. 11; p. 2498
• Main Authors: Wang, Jian, Zhang, Wenjie, Zhang, Yating, Li, Haolin
• Format: Journal Article
• Language: English
• Published: Basel MDPI AG 29.05.2023; MDPI
• Subjects: Acids; acrylic acid; Anionic polymerization; Block copolymers; Hydrolysis; Iron oxides; living anionic polymerization (LAP); Morphology; Nanocomposites; Nanoparticles; Nitrogen; NMR; Nuclear magnetic resonance; organic–inorganic composite nanoparticles; Polyacrylic acid; Polymerization; polymerization-induced self-assembly (PISA); Polymers; Polystyrene resins; Self-assembly; tert-butyl acrylate; China
• ISSN: 2073-4360; 2073-4360
• DOI: 10.3390/polym15112498

Organic–inorganic nanocomposite particles, possessing defined morphologies, represent the next frontier in advanced materials due to their superior collective performance. In this pursuit of efficient preparation of composite nanoparticles, a series of diblock polymers polystyrene-block-poly(tert-butyl acrylate) (PS-b-PtBA) were initially synthesized using the Living Anionic Polymerization-Induced Self-Assembly (LAP PISA) technique. Subsequently, the tert-butyl group on the tert-butyl acrylate (tBA) monomer unit in the diblock copolymer, yielded from the LAP PISA process, was subjected to hydrolysis using trifluoroacetic acid (CF3COOH), transforming it into carboxyl groups. This resulted in the formation of polystyrene-block-poly(acrylic acid) (PS-b-PAA) nano-self-assembled particles of various morphologies. The pre-hydrolysis diblock copolymer PS-b-PtBA produced nano-self-assembled particles of irregular shapes, whereas post-hydrolysis regular spherical and worm-like nano-self-assembled particles were generated. Utilizing PS-b-PAA nano-self-assembled particles that containing carboxyl groups as polymer templates, Fe3O4 was integrated into the core region of the nano-self-assembled particles. This was achieved based on the complexation between the carboxyl groups on the PAA segments and the metal precursors, facilitating the successful synthesis of organic–inorganic composite nanoparticles with Fe3O4 as the core and PS as the shell. These magnetic nanoparticles hold potential applications as functional fillers in the plastic and rubber sectors.