The Chemistry of DPPH · Free Radical and Congeners

Since the discovery in 1922 of 2,2-diphenyl-1-(2,4,6-trinitrophenyl) hydrazyl stable free radical (DPPH ), the chemistry of such open-shell compounds has developed continuously, allowing for both theoretical and practical advances in the free radical chemistry area. This review presents the importan...

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Bibliographic Details
Published inInternational journal of molecular sciences Vol. 22; no. 4; p. 1545
Main Author Ionita, Petre
Format Journal Article
LanguageEnglish
Published Switzerland MDPI AG 03.02.2021
MDPI
Subjects
Congeners
Electron Spin Resonance Spectroscopy
ESR
free radical
Free radicals
Free Radicals - chemistry
Halogens - chemistry
hydrazyl
Models, Chemical
Molecular Structure
Nitrogen dioxide
Nitrogen Dioxide - chemistry
organic synthesis
Oxidation
redox
Review
Solvents
spin
ESR
organic synthesis
spin
free radical
mechanism
hydrazyl
redox
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Summary:Since the discovery in 1922 of 2,2-diphenyl-1-(2,4,6-trinitrophenyl) hydrazyl stable free radical (DPPH ), the chemistry of such open-shell compounds has developed continuously, allowing for both theoretical and practical advances in the free radical chemistry area. This review presents the important, general and modern aspects of the chemistry of hydrazyl free radicals and the science behind it.
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ISSN:1422-0067
1661-6596
1422-0067
DOI:10.3390/ijms22041545