Chemical formation, characterization and properties of polycarbazole
Polycarbazole (PCz) was synthesized by chemical polymerization of carbazole in acetonitrile medium using ammonium persulfate as oxidant. The selection of solvent, concentration of the monomer, composition of the solvent, polymerization time, temperature, and pH were optimized to obtain better qualit...
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Published in | Journal of applied polymer science Vol. 116; no. 1; pp. 147 - 154 |
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Main Authors | , , |
Format | Journal Article |
Language | English |
Published |
Hoboken
Wiley Subscription Services, Inc., A Wiley Company
05.04.2010
Wiley |
Subjects | |
Online Access | Get full text |
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Summary: | Polycarbazole (PCz) was synthesized by chemical polymerization of carbazole in acetonitrile medium using ammonium persulfate as oxidant. The selection of solvent, concentration of the monomer, composition of the solvent, polymerization time, temperature, and pH were optimized to obtain better quality and yield of the polycarbazole. The synthesized polycarbazole was characterized by various techniques such as UV-Visible, FTIR, ¹H-NMR, ¹³C-NMR, COSY, NOESY, and XRD spectroscopy. The solubility of the polycarbazole was tested in various solvents. The thermodynamic stability of the polycarbazole was examined by DSC and TGA-DTA analysis. |
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Bibliography: | http://dx.doi.org/10.1002/app.31511 ark:/67375/WNG-N9C253HQ-5 ArticleID:APP31511 istex:1DAF0995414BC506771068FDA8E3F0DACC92DD4D ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 ObjectType-Article-2 ObjectType-Feature-1 |
ISSN: | 0021-8995 1097-4628 1097-4628 |
DOI: | 10.1002/app.31511 |