Multi Self-Healable UV Shielding Polyurethane/CeO2 Protective Coating: The Effect of Low-Molecular-Weight Polyols

We prepared a series of polyurethane (PU) coatings with defined contents using poly(tetramethylene oxide)glycol (PTMG) with two different molecular weights (i.e., Mn = 2000 and 650), as well as polydimethyl siloxane (PDMS) with a molecular weight of Mn 550. For every coating, maximum adhesive streng...

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Published inPolymers Vol. 12; no. 9; p. 1947
Main Authors Rahman, Mohammad Mizanur, Suleiman, Rami, Zahir, Md. Hasan, Helal, Aasif, Kumar, A. Madhan, Haq, Md. Bashirul
Format Journal Article
LanguageEnglish
Published Basel MDPI AG 28.08.2020
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Abstract We prepared a series of polyurethane (PU) coatings with defined contents using poly(tetramethylene oxide)glycol (PTMG) with two different molecular weights (i.e., Mn = 2000 and 650), as well as polydimethyl siloxane (PDMS) with a molecular weight of Mn 550. For every coating, maximum adhesive strength and excellent self-healing character (three times) were found using 6.775 mol% mixed with low-molecular-weight-based polyols (PU-11-3-3). Defined 1.0 wt% CeO2 was also used for the PU-11-3-3 coating (i.e., PU-11-3-3-CeO2) to obtain UV shielding properties. Both the in situ polymerization and blending processes were separately applied during the preparation of the PU-11-3-3-CeO2 coating dispersion. The in situ polymerization-based coating (i.e., PU-11-3-3-CeO2-P) showed similar self-healing properties. The PU-11-3-3-CeO2-P coating also showed excellent UV shielding in real outdoor exposure conditions.
AbstractList We prepared a series of polyurethane (PU) coatings with defined contents using poly(tetramethylene oxide)glycol (PTMG) with two different molecular weights (i.e., Mn = 2000 and 650), as well as polydimethyl siloxane (PDMS) with a molecular weight of Mn 550. For every coating, maximum adhesive strength and excellent self-healing character (three times) were found using 6.775 mol% mixed with low-molecular-weight-based polyols (PU-11-3-3). Defined 1.0 wt% CeO2 was also used for the PU-11-3-3 coating (i.e., PU-11-3-3-CeO2) to obtain UV shielding properties. Both the in situ polymerization and blending processes were separately applied during the preparation of the PU-11-3-3-CeO2 coating dispersion. The in situ polymerization-based coating (i.e., PU-11-3-3-CeO2-P) showed similar self-healing properties. The PU-11-3-3-CeO2-P coating also showed excellent UV shielding in real outdoor exposure conditions.
We prepared a series of polyurethane (PU) coatings with defined contents using poly(tetramethylene oxide)glycol (PTMG) with two different molecular weights (i.e., M n = 2000 and 650), as well as polydimethyl siloxane (PDMS) with a molecular weight of M n 550. For every coating, maximum adhesive strength and excellent self-healing character (three times) were found using 6.775 mol% mixed with low-molecular-weight-based polyols (PU-11-3-3). Defined 1.0 wt% CeO 2 was also used for the PU-11-3-3 coating (i.e., PU-11-3-3-CeO 2 ) to obtain UV shielding properties. Both the in situ polymerization and blending processes were separately applied during the preparation of the PU-11-3-3-CeO 2 coating dispersion. The in situ polymerization-based coating (i.e., PU-11-3-3-CeO 2 -P) showed similar self-healing properties. The PU-11-3-3-CeO 2 -P coating also showed excellent UV shielding in real outdoor exposure conditions.
Author Rahman, Mohammad Mizanur
Kumar, A. Madhan
Haq, Md. Bashirul
Helal, Aasif
Zahir, Md. Hasan
Suleiman, Rami
AuthorAffiliation 2 Center of Research Excellence in Renewable Energy, King Fahd University of Petroleum and Minerals, Dhahran 31261, Saudi Arabia; hzahir@kfupm.edu.sa
4 Department of Petroleum Engineering, College of Petroleum and Geosciences, King Fahd University of Petroleum and Minerals, Dhahran 31261, Saudi Arabia
1 Center of Research Excellence in Corrosion, King Fahd University of Petroleum and Minerals, Dhahran 31261, Saudi Arabia; ramismob@kfupm.edu.sa (R.S.); madhankumar@kfupm.edu.sa (A.M.K.)
3 Center of Research Excellence in Nanotechnology, King Fahd University of Petroleum and Minerals, Dhahran 31261, Saudi Arabia; aasifh@kfupm.edu.sa
AuthorAffiliation_xml – name: 1 Center of Research Excellence in Corrosion, King Fahd University of Petroleum and Minerals, Dhahran 31261, Saudi Arabia; ramismob@kfupm.edu.sa (R.S.); madhankumar@kfupm.edu.sa (A.M.K.)
– name: 3 Center of Research Excellence in Nanotechnology, King Fahd University of Petroleum and Minerals, Dhahran 31261, Saudi Arabia; aasifh@kfupm.edu.sa
– name: 4 Department of Petroleum Engineering, College of Petroleum and Geosciences, King Fahd University of Petroleum and Minerals, Dhahran 31261, Saudi Arabia
– name: 2 Center of Research Excellence in Renewable Energy, King Fahd University of Petroleum and Minerals, Dhahran 31261, Saudi Arabia; hzahir@kfupm.edu.sa
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Snippet We prepared a series of polyurethane (PU) coatings with defined contents using poly(tetramethylene oxide)glycol (PTMG) with two different molecular weights...
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StartPage 1947
SubjectTerms Adhesive strength
Adhesives
Carbon
Cerium oxides
coating
Coating effects
Humidity
Metal oxides
Molecular weight
Nanoparticles
Polydimethylsiloxane
Polyesters
Polymerization
Polymers
Polyols
polyurethane
Polyurethane resins
Protective coatings
Self healing materials
self-healing
Shielding
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Title Multi Self-Healable UV Shielding Polyurethane/CeO2 Protective Coating: The Effect of Low-Molecular-Weight Polyols
URI https://www.proquest.com/docview/2439616946
https://search.proquest.com/docview/2439630232
https://pubmed.ncbi.nlm.nih.gov/PMC7565661
https://doaj.org/article/06dc4af6e0a84db585787d9672fd0706
Volume 12
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