Improved exfoliation of surface-functionalized graphene oxide by epoxy monomer and enhanced mechanical properties of epoxy nanocomposites

The surface functionalization of graphene oxide (GO) provides an efficient way to improve the dispersion of GO in matrix and the interfacial properties of nanocomposites. In this contribution, GO grafted by bifunctional, trifunctional and tetrafunctional epoxy monomers (E51, AFG90, AG80) was designe...

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Bibliographic Details
Published inJournal of materials science Vol. 57; no. 1; pp. 366 - 382
Main Authors Fan, Jie, Yang, Jiping, Li, Hong, Tian, Junpeng, Ye, Jinrui, Zhao, Yunfeng
Format Journal Article
LanguageEnglish
Published New York Springer US 01.01.2022
Springer
Springer Nature B.V
Subjects
Analysis
Characterization and Evaluation of Materials
Chemistry and Materials Science
Classical Mechanics
Composites & Nanocomposites
Crystallography and Scattering Methods
Dispersion
Epoxy resins
Exfoliation
Grafting
Graphene
Graphite
Interfacial properties
Interlayers
Liquid nitrogen
Materials Science
Mechanical properties
Monomers
Nanocomposites
Polymer Sciences
Room temperature
Solid Mechanics
Thermal cycling
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Summary:The surface functionalization of graphene oxide (GO) provides an efficient way to improve the dispersion of GO in matrix and the interfacial properties of nanocomposites. In this contribution, GO grafted by bifunctional, trifunctional and tetrafunctional epoxy monomers (E51, AFG90, AG80) was designed and three epoxy-functionalized GO (EFGO) samples were acquired and utilized as fillers for epoxy nanocomposites. The chemical, structural and morphological characteristics of EFGO samples were studied. The exfoliation and dispersion state of EFGO in epoxy matrix were characterized. Mechanical properties of the nanocomposites at room temperature (RT), liquid nitrogen temperature (LNT) and after thermal cycling were comprehensively investigated. Results showed that the interlayer distance of EFGO was enlarged with the increase in functionality degree of the grafted epoxy monomers. AG80-functionalized GO (AGGO) with the largest interlayer distance showed the best exfoliation and dispersion in the nanocomposites, while E51-functionalized GO (EGO) showed the worst. Correspondingly, AGGO/epoxy nanocomposites exhibited the highest mechanical properties at RT, LNT and after thermal cycling. The toughening mechanisms of EFGO for epoxy resin were disclosed to better understand the role of epoxy monomers grafted to GO surfaces in the nanocomposites.
ISSN:0022-2461
1573-4803
DOI:10.1007/s10853-021-06580-z