3D-Printed Porous Magnetic Carbon Materials Derived from Metal–Organic Frameworks

Here we report new porous carbon materials obtained by 3D printing from photopolymer compositions with zinc- and nickel-based metal–organic frameworks, ZIF-8 and Ni-BTC, followed by high-temperature pyrolysis. The pyrolyzed materials that retain the shapes of complex objects contain pores, which wer...

Full description

Saved in:
Bibliographic Details
Published inPolymers Vol. 13; no. 22; p. 3881
Main Authors Cherevko, Anton I., Nikovskiy, Igor A., Nelyubina, Yulia V., Skupov, Kirill M., Efimov, Nikolay N., Novikov, Valentin V.
Format Journal Article
LanguageEnglish
Published Basel MDPI AG 10.11.2021
MDPI
Subjects
3-D printers
3D printing
Adsorption
Carbon
Catalysis
Composite materials
Ferromagnetism
High temperature
Medical research
Metal-organic frameworks
Nanoparticles
Nickel
photopolymer
Photopolymers
Polymers
Pore size
porous carbon materials
Porous materials
Pyrolysis
Scanning electron microscopy
Three dimensional printing
Zinc
Germany
Russia
Online AccessGet full text

Cover

More Information
Summary:Here we report new porous carbon materials obtained by 3D printing from photopolymer compositions with zinc- and nickel-based metal–organic frameworks, ZIF-8 and Ni-BTC, followed by high-temperature pyrolysis. The pyrolyzed materials that retain the shapes of complex objects contain pores, which were produced by boiling zinc and magnetic nickel particles. The two thus provided functionalities—large specific surface area and ferromagnetism—that pave the way towards creating heterogenous catalysts that can be easily removed from reaction mixtures in industrial catalytic processes.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:2073-4360
2073-4360
DOI:10.3390/polym13223881