The effect of metals on zeolite crystallization kinetics with relevance to nuclear waste glass corrosion

• Published in: Npj Materials degradation Vol. 7; no. 1; pp. 4 - 7
• Main Authors: Mallette, Adam J., Reiser, Joelle T., Mpourmpakis, Giannis, Motkuri, Radha Kishan, Neeway, James J., Rimer, Jeffrey D.
• Format: Journal Article
• Language: English
• Published: London Nature Publishing Group UK 12.01.2023; Nature Publishing Group; Nature Portfolio
• Subjects: 639/638/263; 639/638/298; Aluminosilicates; Aluminum silicates; Biosphere; Chemistry and Materials Science; Corrosion; Corrosion and Coatings; Crystallization; Electrochemistry; Groundwater; Lithium; Materials Science; Metals; Nucleation; Radioactive materials; Radioactive wastes; Seeds; Structural Materials; Tribology; Zeolites
• ISSN: 2397-2106; 2397-2106
• DOI: 10.1038/s41529-022-00310-9

Geologic disposal of vitrified radioactive material is planned in several countries, but there are remaining uncertainties related to the long-term stability of glass exposed to groundwater. Specifically, the crystallization of aluminosilicate zeolite minerals can accelerate the rate at which glass corrodes and radioactive material is released into the biosphere. In this study, we identify elemental species that may accelerate or suppress zeolite formation using a protocol to examine their effects on zeolite synthesis over a three-day duration. Our results are consistent with previous works demonstrating glass corrosion acceleration in the presence of calcium. Furthermore, we identify two elements—tin and lithium—as inhibitors of zeolite P2 (gismondine, or GIS type) nucleation and, thus, promising components for promoting the long-term durability of glass waste forms.