Structural transitions and guest/host complexing of liquid crystal helical nanofilaments induced by nanoconfinement

• Published in: Science advances Vol. 3; no. 2; p. e1602102
• Main Authors: Kim, Hanim, Ryu, Seong Ho, Tuchband, Michael, Shin, Tae Joo, Korblova, Eva, Walba, David M, Clark, Noel A, Yoon, Dong Ki
• Format: Journal Article
• Language: English
• Published: United States American Association for the Advancement of Science 01.02.2017
• Subjects: Nanomaterials; SciAdv r-articles; helical nanofilament phase; Self-assembly; Guest-host complexing; nematic liquid crystal phase; nano-segregation; nanoconfinement
• ISSN: 2375-2548; 2375-2548
• DOI: 10.1126/sciadv.1602102

A lamellar liquid crystal (LC) phase of certain bent-core mesogenic molecules can be grown in a manner that generates a single chiral helical nanofilament in each of the cylindrical nanopores of an anodic aluminum oxide (AAO) membrane. By introducing guest molecules into the resulting composite chiral nanochannels, we explore the structures and functionality of the ordered guest/host LC complex, verifying the smectic-like positional order of the fluidic nematic LC phase, which is obtained by the combination of the LC organization and the nanoporous AAO superstructure. The guest nematic LC 4'- -pentyl-4-cyanobiphenyl is found to form a distinctive fluid layered ordered LC complex at the nanofilament/guest interface with the host 1,3-phenylene bis[4-(4-nonyloxyphenyliminomethyl)benzoate], where this interface contacts the AAO cylinder wall. Filament growth form is strongly influenced by mixture parameters and pore dimensions.