Investigating Phase‐Change‐Induced Flow in Gas Diffusion Layers in Fuel Cells with X‐ray Computed Tomography

• Published in: Electrochimica acta Vol. 256; no. C; pp. 279 - 290
• Main Authors: Shum, Andrew D., Parkinson, Dilworth Y., Xiao, Xianghui, Weber, Adam Z., Burheim, Odne S., Zenyuk, Iryna V.
• Format: Journal Article
• Language: English
• Published: Oxford Elsevier Ltd 01.12.2017; Elsevier BV; Elsevier
• Subjects: Clusters; Computation; Computed tomography; Diffusion; Diffusion barriers; Diffusion layers; Electrolytic cells; ENERGY STORAGE; Evaporation; Fuel cells; Gas flow; Gaseous diffusion; MATERIALS SCIENCE; Phase transitions; phase-change-induced flow; Polymers; porous media; Studies; Tomography; Visual observation; Water; Water distribution; Water engineering; X-ray tomography; fuel cells; X-ray tomography; phase-change-induced flow; porous media; evaporation
• ISSN: 0013-4686; 1873-3859
• DOI: 10.1016/j.electacta.2017.10.012

The performance of polymer‐electrolyte fuel cells is heavily dependent on proper management of liquid water. One particular reason is that liquid water can collect in the gas diffusion layers (GDLs) blocking the reactant flow to the catalyst layer. This results in increased mass‐transport losses. At higher temperatures, evaporation of water becomes a dominant water‐removal mechanism and specifically phase‐change‐induced (PCI) flow is present due to thermal gradients. This study used synchrotron based micro X‐ray computed tomography (CT) to visualize and quantify the water distribution within gas diffusion layers subject to a thermal gradient. Plotting saturation as a function of through‐plane distance quantitatively shows water redistribution, where water evaporates at hotter locations and condenses in colder locations. The morphology of the GDLs on the micro‐scale, as well as evaporating water clusters, are resolved, indicating that the GDL voids are slightly prolate, whereas water clusters are oblate. From the mean radii of water distributions and visual inspection, it is observed that larger water clusters evaporate faster than smaller ones.