Removal of disperse dye from aqueous solution using waste-derived activated carbon: Optimization study

• Published in: Journal of hazardous materials Vol. 170; no. 2; pp. 612 - 619
• Main Authors: Ahmad, A.A., Hameed, B.H., Ahmad, A.L.
• Format: Journal Article
• Language: English
• Published: Kidlington Elsevier B.V 30.10.2009; Elsevier
• Subjects: Activated carbon; Adsorption; Algorithms; Analysis of Variance; Applied sciences; Azo Compounds; Carbon - analysis; Charcoal - analysis; Chemical engineering; Coloring Agents - analysis; Disperse dye; Exact sciences and technology; Industrial Waste; Microscopy, Electron, Scanning; Models, Chemical; Optimization; Pollution; Porosity; Rattan sawdust; Solutions - analysis; Surface Properties; Temperature; Water Pollutants, Chemical - analysis; Wood; Rattan sawdust; Adsorption; Disperse dye; Activated carbon; Optimization; Dyes; Activation; Modeling; Precursor; Composite material; Design; Impregnation; Experimental design; Preparation; Aqueous solution; Sawdust
• ISSN: 0304-3894; 1873-3336
• DOI: 10.1016/j.jhazmat.2009.05.021

The purpose of this work is to obtain optimal preparation conditions for activated carbons prepared from rattan sawdust (RSAC) for removal of disperse dye from aqueous solution. The RSAC was prepared by chemical activation with phosphoric acid using response surface methodology (RSM). RSM based on a three-variable central composite design was used to determine the effect of activation temperature (400–600 °C), activation time (1–3 h) and H 3PO 4:precursor (wt%) impregnation ratio (3:1–6:1) on C.I. Disperse Orange 30 (DO30) percentage removal and activated carbon yield were investigated. Based on the central composite design, quadratic model was developed to correlate the preparation variables to the two responses. The most influential factor on each experimental design responses was identified from the analysis of variance (ANOVA). The optimum conditions for preparation of RSAC, which were based on response surface and contour plots, were found as follows: temperature of 470 °C, activation time of 2 h and 14 min and chemical impregnation ratio of 4.45.