Efficient reductive dehydration of primary amides to nitriles catalyzed by hydrido thiophenolato iron(II) complexes under hydrosilation conditions

The reductive dehydration of amides to nitriles under hydrosilation conditions with hydrido thiophenolato iron(II) complexes [cis-Fe(H)(SAr)(PMe3)4] (1–4) as catalysts is reported using (EtO)3SiH as an efficient reducing agent in the yields up to 93%. The merits of this catalytic system, the low cat...

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Published inCatalysis communications Vol. 86; pp. 148 - 150
Main Authors Xue, Benjing, Sun, Hongjian, Wang, Yan, Zheng, Tingting, Li, Xiaoyan, Fuhr, Olaf, Fenske, Dieter
Format Journal Article
LanguageEnglish
Published Elsevier B.V 05.11.2016
Subjects
Amide
Dehydration
Iron hydride
Nitrile
Silane
Amide
Nitrile
Dehydration
Iron hydride
Silane
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Abstract The reductive dehydration of amides to nitriles under hydrosilation conditions with hydrido thiophenolato iron(II) complexes [cis-Fe(H)(SAr)(PMe3)4] (1–4) as catalysts is reported using (EtO)3SiH as an efficient reducing agent in the yields up to 93%. The merits of this catalytic system, the low catalyst loadings (2mol%) and the amount of efficient reducing agent (EtO)3SiH, make this method more attractive. [Display omitted] •Hydrido thiophenolato iron(II) complexes.•The reductive dehydration of amides to nitriles.•(EtO)3SiH as a reducing agent.
AbstractList The reductive dehydration of amides to nitriles under hydrosilation conditions with hydrido thiophenolato iron(II) complexes [cis-Fe(H)(SAr)(PMe3)4] (1–4) as catalysts is reported using (EtO)3SiH as an efficient reducing agent in the yields up to 93%. The merits of this catalytic system, the low catalyst loadings (2mol%) and the amount of efficient reducing agent (EtO)3SiH, make this method more attractive. [Display omitted] •Hydrido thiophenolato iron(II) complexes.•The reductive dehydration of amides to nitriles.•(EtO)3SiH as a reducing agent.
Author Sun, Hongjian
Fenske, Dieter
Fuhr, Olaf
Xue, Benjing
Zheng, Tingting
Wang, Yan
Li, Xiaoyan
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Nitrile
Dehydration
Iron hydride
Silane
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Snippet The reductive dehydration of amides to nitriles under hydrosilation conditions with hydrido thiophenolato iron(II) complexes [cis-Fe(H)(SAr)(PMe3)4] (1–4) as...
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SubjectTerms Amide
Dehydration
Iron hydride
Nitrile
Silane
Title Efficient reductive dehydration of primary amides to nitriles catalyzed by hydrido thiophenolato iron(II) complexes under hydrosilation conditions
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