Synthesis, Structural and Sensor Properties of Nanosized Mixed Oxides Based on In2O3 Particles

• Published in: International journal of molecular sciences Vol. 24; no. 2; p. 1570
• Main Authors: Ikim, Mariya I., Gerasimov, Genrikh N., Gromov, Vladimir F., Ilegbusi, Olusegun J., Trakhtenberg, Leonid I.
• Format: Journal Article
• Language: English
• Published: Basel MDPI AG 13.01.2023; MDPI
• Subjects: Binary mixtures; Catalytic activity; Cerium oxides; Chemisorption; Cobalt oxides; Composite materials; conductivity; Crystal lattices; Efficiency; Gases; impregnation method; Indium; indium oxide; Indium oxides; Metal oxides; Mixed oxides; nanocomposite; Nanoparticles; Oxides; Review; sensor response; Sensors; Tin dioxide; tin oxide; Zinc oxide; Zirconium dioxide
• ISSN: 1422-0067; 1661-6596; 1422-0067
• DOI: 10.3390/ijms24021570

The paper considers the relationship between the structure and properties of nanostructured conductometric sensors based on binary mixtures of semiconductor oxides designed to detect reducing gases in the environment. The sensor effect in such systems is determined by the chemisorption of molecules on the surface of catalytically active particles and the transfer of chemisorbed products to electron-rich nanoparticles, where these products react with the analyzed gas. In this regard, the role is evaluated of the method of synthesizing the composites, the catalytic activity of metal oxides (CeO2, SnO2, ZnO), and the type of conductivity of metal oxides (Co3O4, ZrO2) in the sensor process. The effect of oxygen vacancies present in the composites on the performance characteristics is also considered. Particular attention is paid to the influence of the synthesis procedure for preparing sensitive layers based on CeO2–In2O3 on the structure of the resulting composites, as well as their conductive and sensor properties.