Boosting the Electrocatalytic CO2 Reduction Reaction by Nanostructured Metal Materials via Defects Engineering

• Published in: Nanomaterials (Basel, Switzerland) Vol. 12; no. 14; p. 2389
• Main Authors: Zhao, Shuangyang, Liu, Aihua, Li, Yonghe, Wen, Yanyan, Gao, Xiaoqian, Chen, Qiaoli
• Format: Journal Article
• Language: English
• Published: Basel MDPI AG 13.07.2022; MDPI
• Subjects: Carbon; Carbon dioxide; Catalytic activity; Chemical reduction; Chemical synthesis; Climate change; CO2 reduction reaction; Defects; electrocatalytic; Electrochemistry; Electron microscopy; Grain boundaries; metal; Metals; Microscopy; Nanocrystals; Nanomaterials; Nanotechnology; Point defects; Review; Selectivity; Symmetry
• ISSN: 2079-4991; 2079-4991
• DOI: 10.3390/nano12142389

Electrocatalytic CO2 reduction reaction (CO2RR) is one of the most effective methods to convert CO2 into useful fuels. Introducing defects into metal nanostructures can effectively improve the catalytic activity and selectivity towards CO2RR. This review provides the recent progress on the use of metal nanomaterials with defects towards electrochemical CO2RR and defects engineering methods. Accompanying these ideas, we introduce the structure of defects characterized by electron microscopy techniques as the characterization and analysis of defects are relatively difficult. Subsequently, we present the intrinsic mechanism of how the defects affect CO2RR performance. Finally, to promote a wide and deep study in this field, the perspectives and challenges concerning defects engineering in metal nanomaterials towards CO2RR are put forward.