Micro-particle entrainment from density mismatched liquid carrier system

• Published in: Scientific reports Vol. 12; no. 1; pp. 9806 - 13
• Main Authors: Shovon, S. M. Naser, Alam, Adeeb, Gramlich, William, Khoda, Bashir
• Format: Journal Article
• Language: English
• Published: London Nature Publishing Group UK 13.06.2022; Nature Publishing Group; Nature Portfolio
• Subjects: 639/166/988; 639/766/419; Coatings; Entrainment; Geometry; Humanities and Social Sciences; Manufacturing; Manufacturing industry; multidisciplinary; Polymers; Rheology; Science; Science (multidisciplinary); Viscosity
• ISSN: 2045-2322; 2045-2322
• DOI: 10.1038/s41598-022-14162-5

Micro-scale inorganic particles (d > 1 µm) have reduced surface area and higher density, making them negatively buoyant in most dip-coating mixtures. Their controlled delivery in hard-to-reach places through entrainment is possible but challenging due to the density mismatch between them and the liquid matrix called liquid carrier system (LCS). In this work, the particle transfer mechanism from the complex density mismatching mixture was investigated. The LCS solution was prepared and optimized using a polymer binder and an evaporating solvent. The inorganic particles were dispersed in the LCS by stirring at the just suspending speed to maintain the pseudo suspension characteristics for the heterogeneous mixture. The effect of solid loading and the binder volume fraction on solid transfer has been reported at room temperature. Two coating regimes are observed (i) heterogeneous coating where particle clusters are formed at a low capillary number and (ii) effective viscous regime, where full coverage can be observed on the substrate. ‘Zero’ particle entrainment was not observed even at a low capillary number of the mixture, which can be attributed to the presence of the binder and hydrodynamic flow of the particles due to the stirring of the mixture. The critical film thickness for particle entrainment is h ∗ = 0.16 a for 6.5% binder and h ∗ = 0.26 a for 10.5% binder, which are smaller than previously reported in literature. Furthermore, the transferred particle matrices closely follow the analytical expression (modified LLD) of density matching suspension which demonstrate that the density mismatch effect can be neutralized with the stirring energy. The findings of this research will help to understand this high-volume solid transfer technique and develop novel manufacturing processes.