Methods for synthesizing diethyl carbonate from ethanol and supercritical carbon dioxide by one-pot or two-step reactions in the presence of potassium carbonate

• Published in: The Journal of supercritical fluids Vol. 50; no. 1; pp. 46 - 53
• Main Authors: Gasc, Fabien, Thiebaud-Roux, Sophie, Mouloungui, Zephirin
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01.08.2009; Elsevier
• Subjects: Chemical and Process Engineering; Diethyl carbonate; Diethyl ether; Engineering Sciences; Ethanol; Food engineering; Hybrid carbonate; Life Sciences; One-pot process; Potassium carbonate; Supercritical carbon dioxide; Two-step reaction; Supercritical carbon dioxide; Diethyl carbonate; Diethyl ether; Ethanol; One-pot process; Two-step reaction; Hybrid carbonate; Potassium carbonate
• ISSN: 0896-8446; 1872-8162
• DOI: 10.1016/j.supflu.2009.03.008

Carbon dioxide sequestration was studied by synthesizing diethyl carbonate (DEC) from ethanol and CO 2 under supercritical conditions in the presence of potassium carbonate as a base. The co-reagent was ethyl iodide or a concentrated strong acid. This sequestration reaction occurs in two steps, which were studied separately and in a one-pot reaction. An organic–inorganic carbonate hybrid, potassium ethyl carbonate (PEC) is generated at the end of the first step. This intermediate was characterized and was found to be a target molecule for CO 2 capture. Different co-reactants, such as ethyl iodide and concentrated strong Brönsted acid, were compared in the second step and used to investigate the reactivity of the hybrid. With ethyl iodide as the co-reactant, one-pot DEC synthesis gave higher yields (46%) than two-step production. The supercritical CO 2 acts as a swelling solvent and compatibilizing agent in the reaction medium, favoring interactions between ethanol and CO 2 and between PEC and ethyl iodide. The use of a phase transfer catalyst (PTC) increased DEC production (yield 51%) without increasing the amount of diethyl ether (DEE) produced as a by-product (yield 2%).