Plasmonic-enhanced photocatalysis reactions using gold nanostructured films

• Published in: RSC advances Vol. 1; no. 38; pp. 22324 - 2233
• Main Authors: Ibrahem, Mohammed A, Rasheed, Bassam G, Mahdi, Rahman I, Khazal, Taha M, Omar, Maryam M, O'Neill, Mary
• Format: Journal Article
• Language: English
• Published: England Royal Society of Chemistry 10.06.2020; The Royal Society of Chemistry
• Subjects: Broadband; Catalytic activity; Chemistry; Computer architecture; Glass substrates; Hot electrons; Low temperature; Methylene blue; Nanostructure; Photocatalysis; Photocatalysts; Photodegradation; Plasmonics; Size distribution; Surface plasmon resonance; Surface treatment; Titanium dioxide
• ISSN: 2046-2069; 2046-2069
• DOI: 10.1039/d0ra03858j

This work shows the enhancement of the visible photocatalytic activity of TiO 2 NPs film using the localized surface plasmonic resonance of Au nanostructures. We adopted a simple yet effective surface treatment to tune the size distribution, and plasmonic resonance spectrum of Au nanostructured films on glass substrates, by hot plate annealing in air at low temperatures. A hybrid photocatalytic film of TiO 2 :Au is utilized to catalyse a selective photodegradation reaction of Methylene Blue in solution. Irradiation at the plasmonic resonance wavelength of the Au nanostructures provides more effective photodegradation compared to broadband artificial sunlight of significantly higher intensity. This improvement is attributed to the active contribution of the plasmonic hot electrons injected into the TiO 2 . The broadband source initiates competing photoreactions in the photocatalyst, so that carrier transfer from the catalyst surface to the solution is less efficient. The proposed hybrid photocatalyst can be integrated with a variety of device architectures and designs, which makes it highly attractive for low-cost photocatalysis applications. This work shows the enhancement of the visible photocatalytic activity of TiO 2 NPs film using the localized surface plasmonic resonance of Au nanostructures.