The First Efficient Hydroaminomethylation with Ammonia: With Dual Metal Catalysts and Two-Phase Catalysis to Primary Amines

Primary and unbranched secondary amines are obtained by the highly selective hydroaminomethylation of olefins with ammonia [Eq. (a)]. The selectivity is readily controlled with a new dual Rh/Ir catalyst in a two‐phase system.

Saved in:
Bibliographic Details
Published inAngewandte Chemie International Edition Vol. 38; no. 16; pp. 2372 - 2375
Main Authors Zimmermann, Burkhard, Herwig, Jürgen, Beller, Matthias
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag GmbH 16.08.1999
WILEY‐VCH Verlag GmbH
Wiley
Subjects
Amines
Ammonia
Catalysis
Catalysts
Chemistry
Chemistry, Multidisciplinary
Hydroaminomethylations
Hydroformylations
Hydrogenations
Olefins
Physical Sciences
Science & Technology
Selectivity
Two-phase catalysis
AMINOMETHYLATION
HYDROGENATION
ONE-POT SYNTHESIS
amines
hydroformylations
hydroaminomethylations
two-phase catalysis
DINUCLEAR RHODIUM COMPLEXES
ALKENES
AMINATION
DI(MU-CHLORO)BIS(ETA-1,5-CYCLOOCTADIENE)DIRHODIUM
WATER-SOLUBLE LIGANDS
OLEFINS
hydrogenations
SYNGAS
Online AccessGet full text

Cover

More Information
Summary:Primary and unbranched secondary amines are obtained by the highly selective hydroaminomethylation of olefins with ammonia [Eq. (a)]. The selectivity is readily controlled with a new dual Rh/Ir catalyst in a two‐phase system.
Bibliography:ark:/67375/WNG-B937XVVF-M
ArticleID:ANIE2372
istex:25003EE5342804510723BEB416EFD74F70C9A932
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1433-7851
1521-3773
DOI:10.1002/(SICI)1521-3773(19990816)38:16<2372::AID-ANIE2372>3.0.CO;2-H