The shear mode of multilayer graphene
Raman spectroscopy has already proved to be a powerful tool for studying the properties of single graphene layers. It is now shown that this technique can also provide information on the interaction between graphene sheets in multilayered graphene structures. In particular, a Raman peak correspondin...
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Published in | Nature materials Vol. 11; no. 4; pp. 294 - 300 |
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Main Authors | , , , , , , , , , , , , |
Format | Journal Article |
Language | English |
Published |
London
Nature Publishing Group UK
05.02.2012
Nature Publishing Group |
Subjects | |
Online Access | Get full text |
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Summary: | Raman spectroscopy has already proved to be a powerful tool for studying the properties of single graphene layers. It is now shown that this technique can also provide information on the interaction between graphene sheets in multilayered graphene structures. In particular, a Raman peak corresponding to the interlayer shear mode, and probably linked to the interlayer coupling, is unveiled.
The quest for materials capable of realizing the next generation of electronic and photonic devices continues to fuel research on the electronic, optical and vibrational properties of graphene. Few-layer graphene (FLG) flakes with less than ten layers each show a distinctive band structure. Thus, there is an increasing interest in the physics and applications of FLGs. Raman spectroscopy is one of the most useful and versatile tools to probe graphene samples. Here, we uncover the interlayer shear mode of FLGs, ranging from bilayer graphene (BLG) to bulk graphite, and suggest that the corresponding Raman peak measures the interlayer coupling. This peak scales from ~43 cm
−1
in bulk graphite to ~31 cm
−1
in BLG. Its low energy makes it sensitive to near-Dirac point quasiparticles. Similar shear modes are expected in all layered materials, providing a direct probe of interlayer interactions. |
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Bibliography: | ObjectType-Article-2 SourceType-Scholarly Journals-1 ObjectType-Feature-1 content type line 23 SourceType-Other Sources-1 content type line 63 ObjectType-Correspondence-1 |
ISSN: | 1476-1122 1476-4660 |
DOI: | 10.1038/nmat3245 |