Exfoliated polypyrrole-organically modified montmorillonite clay nanocomposite as a potential adsorbent for Cr(VI) removal

• Published in: Chemical engineering journal (Lausanne, Switzerland : 1996) Vol. 222; pp. 186 - 197
• Main Authors: Setshedi, Katlego Zebedius, Bhaumik, Madhumita, Songwane, Segametsi, Onyango, Maurice S., Maity, Arjun
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01.04.2013
• Subjects: Adsorbents; Adsorption; chemical engineering; Chromium(VI); clay; Clay (material); desorption; Equilibrium isotherm; Exfoliated nanocomposite; groundwater; ions; Kinetics; montmorillonite; Nanocomposites; Nanomaterials; Nanostructure; Numerical control; polymer nanocomposites; polymerization; polymers; Polypyrrole; sorption isotherms; surface area; Surface chemistry; temperature; toxicity; water pollution; Kinetics; Adsorption; Chromium(VI); Equilibrium isotherm; Exfoliated nanocomposite; Polypyrrole
• ISSN: 1385-8947; 1873-3212
• DOI: 10.1016/j.cej.2013.02.061

► Exfoliated PPy-OMMT NC was synthesized for Cr(VI) removal. ► Enhanced adsorption capacity was found using PPy-OMMT NC clay. ► Adsorption of Cr(VI) followed the Langmuir isotherm model and it was rapid. ► Results from co-existing ions experiment showed selective Cr(VI) adsorption. ► PPy-OMMT NC can be used for three consecutive adsorption cycles. Exfoliated polypyrrole-organically modified montmorillonite clay nanocomposite (PPy-OMMT NC), was prepared as a potential adsorbent, via in situ polymerization of pyrrole monomer for adsorption of toxic Cr(VI) from aqueous solution. The WAXD and SAXS results indicated that the clay sheets were exfoliated in the prepared nanocomposite. HR-TEM results showed good dispersion of the clay into the polymer matrix. The presence of the PPy polymer in the nanocomposite and adsorption of Cr(VI) onto the nanocomposite were confirmed using ATR-FTIR. Using the BET method, an improved surface area was observed for the PPy-OMMT NC compared to native clay. Batch adsorption studies whereby the pH, initial Cr(VI) concentration, sorbent dosage and temperature were varied, revealed that Cr(VI) adsorption process was rapid, spontaneous in nature and favoured with increased temperature at pH 2. The kinetic data fitted well to the pseudo second order kinetic model while the equilibrium data was satisfactorily described by the Langmuir isotherm. The Langmuir maximum adsorption capacity of Cr(VI) onto PPy-OMMT NC at pH 2.0 was found to be 112.3, 119.34, 176.2 and 209.6mg/g at 292K, 298K, 308K and 318K, respectively. The selective adsorption of Cr(VI) was demonstrated in binary adsorption systems with co-existing ions. Moreover, desorption experiments revealed that the nanocomposite can be reused effectively for two consecutive adsorption–desorption cycles without any loss of its original capacity. Groundwater test results showed that the nanocomposite is a potential adsorbent for Cr(VI) ion removal from contaminated water sources.