Transition Metal‐Catalyzed Reactions Involving Oximes

Oximes are an easily prepared and transformed unit, which are widely used in organic synthesis. The oximes, including oxime ethers and esters, could realize various transformations, such as C–H bond activation, Heck‐type reactions, N–O bond cleavage/C–N bond formation, O–H bond cleavage and coupling...

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Bibliographic Details
Published inAdvanced synthesis & catalysis Vol. 359; no. 5; pp. 710 - 771
Main Authors Li, Jun, Hu, Yitian, Zhang, Daopeng, Liu, Qing, Dong, Yunhui, Liu, Hui
Format Journal Article
LanguageEnglish
Published Heidelberg Wiley Subscription Services, Inc 06.03.2017
Subjects
Activation
Bonding
catalysis
Chemical reactions
Cleavage
Couplings
C–H activation
Esters
Ethers
Heck reaction
Hydrogen bonds
Oximes
Transformations
transition metal catalysts
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Summary:Oximes are an easily prepared and transformed unit, which are widely used in organic synthesis. The oximes, including oxime ethers and esters, could realize various transformations, such as C–H bond activation, Heck‐type reactions, N–O bond cleavage/C–N bond formation, O–H bond cleavage and couplings. However, there is no a comprehensive review on this subject. Herein, we summarize the recent advances over the past 15 years in transition metal‐catalyzed reactions involving oximes, focusing on the reaction scope, limitations and mechanisms.
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ISSN:1615-4150
1615-4169
DOI:10.1002/adsc.201600807