Modification of mechanical properties of recycled polypropylene from post-consumer containers

• Published in: Waste management (Elmsford) Vol. 28; no. 12; pp. 2456 - 2464
• Main Authors: Brachet, P., Høydal, L.T., Hinrichsen, E.L., Melum, F.
• Format: Journal Article
• Language: English
• Published: Kidlington Elsevier Ltd 01.12.2008; Elsevier
• Subjects: Applied sciences; Conservation of Natural Resources - methods; Exact sciences and technology; Other wastes and particular components of wastes; Pollution; Polypropylenes - chemistry; Product Packaging; Waste Products; Wastes; Thermal properties; Differential scanning calorimetry; Blending; Upgrading; Trend analysis; Packaging; Mechanical properties; Raw materials; Recycled material; Compatibility
• ISSN: 0956-053X; 1879-2456
• DOI: 10.1016/j.wasman.2007.10.021

This study is conducted to look at the modification of mechanical properties of recycled polypropylene (PP) from post-consumer containers with the addition of stabilizers, elastomer (ethylene–octene rubber, EOR) and calcium carbonate (CaCO3). The mechanical and thermal properties of the blends were evaluated. The results showed limited changes with the addition of elastomer and calcium carbonate on the mechanical properties of the recycled polypropylene. Some differences were observed, but the trends were not reproducible over the different compositions. DSC analysis confirmed the presence of polyethylene (PE) in the recycled polypropylene. The polyethylene impurity and the presence of many different qualities of polypropylene in the recycled material may have prevented any possible improvement in the mechanical properties by the addition of EOR and CaCO3, improvements seen in previous studies on virgin polypropylene. The compatibility of the different homopolymers and copolymers of PP used in consumer packaging is not known, while polyethylene and polypropylene are known not to be miscible with each other. The mixture of qualities and materials may explain such a poor blending. Reusing and upgrading of recycled PP from post-consumer containers would therefore first require a better sorting of the post-consumer waste. The use of an adequate compatibilizer that would allow a uniform and homogeneous blending of the raw material mixture might enhance the mechanical properties.