Syntheses and Ligating Properties of Molybdocene Alkoxides-The First Heterodimetallic Alkoxide Containing Molybdenum and Bismuth

Fluorinated alkoxide ligands RO− (R=CH(CF3)2) are the key to the isolation of compounds of the type [Cp2Mo(OR)2]. When electron‐donating groups R are employed, the Mo(OR)2 moiety can, and necessarily has to, serve as a ligand for Lewis acidic fragments, allowing the isolation and structural characte...

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Published inAngewandte Chemie (International ed.) Vol. 38; no. 8; pp. 1105 - 1108
Main Authors Hunger, Marc, Limberg, Christian, Kircher, Peter
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag GmbH 19.04.1999
WILEY‐VCH Verlag GmbH
Subjects
Alkoxides
Bismuth
Fluorination
Fragments
Heterodimetallic compounds
Ligands
Molybdenum
Structural analysis
Bismuth
Alkoxides
Molybdenum
Heterodimetallic compounds
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Summary:Fluorinated alkoxide ligands RO− (R=CH(CF3)2) are the key to the isolation of compounds of the type [Cp2Mo(OR)2]. When electron‐donating groups R are employed, the Mo(OR)2 moiety can, and necessarily has to, serve as a ligand for Lewis acidic fragments, allowing the isolation and structural characterization of the first heterodimetallic alkoxide containing a Bi and a Mo center (1).
Bibliography:ArticleID:ANIE1105
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ISSN:1433-7851
1521-3773
DOI:10.1002/(SICI)1521-3773(19990419)38:8<1105::AID-ANIE1105>3.0.CO;2-U