Syntheses and Ligating Properties of Molybdocene Alkoxides-The First Heterodimetallic Alkoxide Containing Molybdenum and Bismuth
Fluorinated alkoxide ligands RO− (R=CH(CF3)2) are the key to the isolation of compounds of the type [Cp2Mo(OR)2]. When electron‐donating groups R are employed, the Mo(OR)2 moiety can, and necessarily has to, serve as a ligand for Lewis acidic fragments, allowing the isolation and structural characte...
Saved in:
Published in | Angewandte Chemie (International ed.) Vol. 38; no. 8; pp. 1105 - 1108 |
---|---|
Main Authors | , , |
Format | Journal Article |
Language | English |
Published |
Weinheim
WILEY-VCH Verlag GmbH
19.04.1999
WILEY‐VCH Verlag GmbH |
Subjects | |
Online Access | Get full text |
Cover
Loading…
Summary: | Fluorinated alkoxide ligands RO− (R=CH(CF3)2) are the key to the isolation of compounds of the type [Cp2Mo(OR)2]. When electron‐donating groups R are employed, the Mo(OR)2 moiety can, and necessarily has to, serve as a ligand for Lewis acidic fragments, allowing the isolation and structural characterization of the first heterodimetallic alkoxide containing a Bi and a Mo center (1). |
---|---|
Bibliography: | ArticleID:ANIE1105 ark:/67375/WNG-G382HDL3-5 istex:861AAD724BC6950E72131D420E9C925EF7FC8CC4 ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
ISSN: | 1433-7851 1521-3773 |
DOI: | 10.1002/(SICI)1521-3773(19990419)38:8<1105::AID-ANIE1105>3.0.CO;2-U |