Aromatic Polyhedral Hydroxyborates: Bridging Boron Oxides and Boron Hydrides
No explosion, but per‐B‐hydroxylation occurs if the icosahedral boron hydrides [closo‐B12H12]2− (see picture), [closo‐CB11H12]−, or closo‐1,12‐(CH2OH)2‐1,12‐C2B10H10 are refluxed in 30 % hydrogen peroxide. Thus, the three isoelectronic species [closo‐B12(OH)12]2−, [closo‐1‐H‐1‐CB11(OH)11]−, and clos...
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Published in | Angewandte Chemie (International ed.) Vol. 38; no. 8; pp. 1061 - 1064 |
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Main Authors | , , , |
Format | Journal Article |
Language | English |
Published |
Weinheim
WILEY-VCH Verlag GmbH
19.04.1999
WILEY‐VCH Verlag GmbH |
Subjects | |
Online Access | Get full text |
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Summary: | No explosion, but per‐B‐hydroxylation occurs if the icosahedral boron hydrides [closo‐B12H12]2− (see picture), [closo‐CB11H12]−, or closo‐1,12‐(CH2OH)2‐1,12‐C2B10H10 are refluxed in 30 % hydrogen peroxide. Thus, the three isoelectronic species [closo‐B12(OH)12]2−, [closo‐1‐H‐1‐CB11(OH)11]−, and closo‐1,12‐H2‐1,12‐C2B10(OH)10 were obtained. ○=BH, ○=BOH. |
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Bibliography: | istex:E59B552D995ECADF7C00BE3AB373D60EA55AE3A9 ArticleID:ANIE1061 ark:/67375/WNG-WZKJTV5T-Q ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
ISSN: | 1433-7851 1521-3773 |
DOI: | 10.1002/(SICI)1521-3773(19990419)38:8<1061::AID-ANIE1061>3.0.CO;2-B |