Infrared spectroscopy refines chronological assessment, depositional environment and pyrolysis conditions of archeological charcoals

• Published in: Scientific reports Vol. 10; no. 1; p. 12427
• Main Authors: Smidt, E., Tintner, J., Nelle, O., Oliveira, R. R., Patzlaff, R., Novotny, E. H., Klemm, S.
• Format: Journal Article
• Language: English
• Published: London Nature Publishing Group UK 24.07.2020; Nature Publishing Group
• Subjects: 639/301; 704/47; Age; Aging; Carbon; Carboxylic acids; Charcoal; Cultural heritage; Experiments; Humanities and Social Sciences; Infrared spectroscopy; multidisciplinary; Organic compounds; Oxidation; Pore size; Pyrolysis; Science; Science (multidisciplinary); Soil erosion; Vibrations
• ISSN: 2045-2322; 2045-2322
• DOI: 10.1038/s41598-020-69445-6

Based on infrared spectral characteristics, six archeological sample sets of charcoals from German (5) and Brazilian (1) sites, covering the time span from the nineteenth century CE to 3950 BCE, were compared to a chronological (present to the fifteenth century BCE) series of Austrian charcoals. A typical chronological trend of several bands (stretch vibrations: O–C–O of carboxylates at 1,585–1,565 and 1,385–1,375 cm −1 , C–O carboxylic acids at 1,260–1,250 cm −1 ) that indicate oxidation and subsequently increasing hydrophilicity (O–H stretch vibration at about 3,400 cm −1 ) was also contained in the archive samples. Three sample sets fit in the typical band development according to their age. For three sample sets this conformity was not observed. Despite the age of two sample sets (3950–2820 BCE), most charcoals were assigned to the Modern Period. Apart from the high degree of carbonization, anaerobic depositional conditions over a longer period of time seem to contribute to the surprising conservation. Non-removable mineral components in charcoals, as observed in a third sample set, strongly influence infrared band intensities and positions of organic compounds. The role of inorganic components in terms of charcoal aging, and the information we can obtain from spectral characteristics in an archeological context, are discussed.