NaOH-Catalyzed Imine Synthesis: Aerobic Oxidative Coupling of Alcohols and Amines

The convenient transition‐metal‐free synthesis of imines through oxidative coupling of alcohols and amines is reported. The reaction is catalyzed by NaOH (10 mol‐%) and is performed with air as an oxidant in the absence of any co‐solvent. The convenient transition‐metal‐free synthesis of imines thro...

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Published inEuropean journal of organic chemistry Vol. 2012; no. 24; pp. 4457 - 4460
Main Authors Donthiri, Ramachandra Reddy, Patil, Rajendra D., Adimurthy, Subbarayappa
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 01.08.2012
WILEY‐VCH Verlag
Wiley
Wiley-VCH
Wiley Subscription Services, Inc
Subjects
Alcohols
Amines
Catalysis
Catalytic reactions
Chemistry
Chemistry, Organic
Exact sciences and technology
General and physical chemistry
Heterogeneous catalysis
Imines
Oxidative coupling
Physical Sciences
Science & Technology
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
Heterogeneous catalysis
Amines
Imines
ONE-POT SYNTHESIS
N-ALKYLATION
RUTHENIUM
Oxidative coupling
SECONDARY-AMINES
EFFICIENT
Alcohols
HYDRIDE
AMIDES
Catalytic reaction
Alcohol
Transition metal
Air
Aerobe
Imine
Oxidant
Sodium hydroxide
Cosolvent
Amine
Chemical synthesis
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Abstract The convenient transition‐metal‐free synthesis of imines through oxidative coupling of alcohols and amines is reported. The reaction is catalyzed by NaOH (10 mol‐%) and is performed with air as an oxidant in the absence of any co‐solvent. The convenient transition‐metal‐free synthesis of imines through oxidative coupling of alcohols and amines is reported. The reaction is catalyzed by NaOH (10 mol‐%) and is performed with air as an oxidant in the absence of any co‐solvent.
AbstractList The convenient transition‐metal‐free synthesis of imines through oxidative coupling of alcohols and amines is reported. The reaction is catalyzed by NaOH (10 mol‐%) and is performed with air as an oxidant in the absence of any co‐solvent. The convenient transition‐metal‐free synthesis of imines through oxidative coupling of alcohols and amines is reported. The reaction is catalyzed by NaOH (10 mol‐%) and is performed with air as an oxidant in the absence of any co‐solvent.
The convenient transition‐metal‐free synthesis of imines through oxidative coupling of alcohols and amines is reported. The reaction is catalyzed by NaOH (10 mol‐%) and is performed with air as an oxidant in the absence of any co‐solvent.
The convenient transition-metal-free synthesis of imines through oxidative coupling of alcohols and amines is reported. The reaction is catalyzed by NaOH (10 mol-%) and is performed with air as an oxidant in the absence of any co-solvent. [PUBLICATION ABSTRACT]
Author Patil, Rajendra D.
Adimurthy, Subbarayappa
Donthiri, Ramachandra Reddy
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  givenname: Rajendra D.
  surname: Patil
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  givenname: Subbarayappa
  surname: Adimurthy
  fullname: Adimurthy, Subbarayappa
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  organization: Analytical Science Division, Central Salt & Marine Chemicals Research Institute, (CSIR), G.B. Marg, Bhavnagar-364021 India, Fax: +91-278-2567562
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Issue 24
Keywords Heterogeneous catalysis
Amines
Imines
ONE-POT SYNTHESIS
N-ALKYLATION
RUTHENIUM
Oxidative coupling
SECONDARY-AMINES
EFFICIENT
Alcohols
HYDRIDE
AMIDES
Catalytic reaction
Alcohol
Transition metal
Air
Aerobe
Imine
Oxidant
Sodium hydroxide
Cosolvent
Amine
Chemical synthesis
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e_1_2_6_39_2
e_1_2_6_14_2
e_1_2_6_37_2
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Bolin Z. (e_1_2_6_18_2) 2007
e_1_2_6_21_2
e_1_2_6_27_2
e_1_2_6_44_2
e_1_2_6_25_2
e_1_2_6_46_2
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Snippet The convenient transition‐metal‐free synthesis of imines through oxidative coupling of alcohols and amines is reported. The reaction is catalyzed by NaOH (10...
The convenient transition-metal-free synthesis of imines through oxidative coupling of alcohols and amines is reported. The reaction is catalyzed by NaOH (10...
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SubjectTerms Alcohols
Amines
Catalysis
Catalytic reactions
Chemistry
Chemistry, Organic
Exact sciences and technology
General and physical chemistry
Heterogeneous catalysis
Imines
Oxidative coupling
Physical Sciences
Science & Technology
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
Title NaOH-Catalyzed Imine Synthesis: Aerobic Oxidative Coupling of Alcohols and Amines
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https://onlinelibrary.wiley.com/doi/abs/10.1002%2Fejoc.201200716
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Volume 2012
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