Supercritical propanol, a possible route to composite carbon fibre recovery: A viability study

• Published in: Composites. Part A, Applied science and manufacturing Vol. 37; no. 11; pp. 2171 - 2175
• Main Authors: Hyde, Jason R., Lester, Edward, Kingman, Sam, Pickering, Stephen, Wong, Kok Hoong
• Format: Journal Article
• Language: English
• Published: Oxford Elsevier Ltd 01.01.2006; Elsevier
• Subjects: A. Carbon fibre; A. Surfaces; Applied sciences; B. Strength; Exact sciences and technology; Polymer industry, paints, wood; Technology of polymers; Waste treatment; B. Strength; A. Carbon fibre; A. Surfaces; Material recovery; Heat treatment; Waste treatment; Fiber reinforced material; Epoxy resin; Mechanical properties; Propanol; Experimental study; Solvent extraction; Mineral fiber; Composite material; Tensile strength; Chemical treatment; Supercritical solvent; Plastic waste; Carbon fiber
• ISSN: 1359-835X; 1878-5840
• DOI: 10.1016/j.compositesa.2005.12.006

Supercritical propanol has been used to extract and remove the epoxy resin from the surface of a carbon fibre composite material. The process appeared to be effective when operating above 450 °C and above 50 bar. The recovered fibres were found to be virtually as strong, in terms of tensile strength, as the virgin fibres indicating that little had been done to damage their structural integrity. One advantage of this method is that the polymer, as well as the fibre material, can be recovered. The polymer was analysed to investigate what chemical transformations had occurred during treatment. It is seems likely that the amide cross-linker is broken in the polymer to release a residue with a relatively high molecular weight.