Effect of clay aggregation on water diffusivity using low field NMR

• Published in: Journal of colloid and interface science Vol. 327; no. 1; pp. 84 - 93
• Main Authors: Guichet, Xavier, Fleury, Marc, Kohler, Eric
• Format: Journal Article
• Language: English
• Published: San Diego, CA Elsevier Inc 01.11.2008; Elsevier
• Subjects: Chemistry; Clay particles; Colloid materials; Colloidal state and disperse state; Diffusion; Electro-chemical properties; Exact sciences and technology; General and physical chemistry; Microstructure; NMR; Porous materials; Smectite; Surface physical chemistry; Transport properties; NMR; Transport properties; Electro-chemical properties; Clay particles; Smectite; Porous materials; Colloid materials; Diffusion; Microstructure; Water; NMR spectrometry; Porous material; Relaxation time; Aggregation; Particle; Chemical properties; Clay; Suspension; Colloid; Diffusivity; Salinity; Thickness; Debye length; Distribution; Aqueous solution; Aggregate
• ISSN: 0021-9797; 1095-7103
• DOI: 10.1016/j.jcis.2008.08.013

Water diffusivity D measured by using NMR techniques in Na-smectite suspensions decreases with increasing smectite fraction (up to 50 wt%), but increases with increasing salinity (NaCl or CaCl 2 aqueous solutions) at a fixed clay fraction. The increase, larger for CaCl 2 solutions, is explained by aggregation of clay particles when high salinities are reached. Macroscopic organisation of dense mixtures of clay and aqueous solutions can be inferred by T 2 transverse NMR relaxation times which are sensitive to the volume to surface ratio. Dispersed suspensions exhibit mono-modal T 2 distributions, whereas bimodal T 2 distributions are observed for flocculated systems. The bimodal T 2 distributions are interpreted as a measurement of the spacing between clay particles within aggregates and between aggregates. Finally, the diffusion data can be gathered in an unique curve using the Debye length and the measured spacing between particles. When the thickness of the electro-diffuse layer (Debye length) is of the same order as the spacing between clay particles, the water diffusivity decreases. Otherwise it is constant at about 2.22 ± 0.25 × 10 −9 m 2 / s . This last result illustrates clearly the effect of electro-chemical properties of smectite on water diffusivity. Normalised water diffusivity versus the ratio R l of the two characteristic lengths of the suspension, i.e. the apparent spacing between clay particles divided by the Debye length.