Tailoring vapor-deposited ZnMg–Zn bilayer coating for steels by diffusion-driven phase transformation
This study reports a “high temperature fast annealing” approach to tailor the microstructure of ZnMg–Zn bilayer coatings through a diffusion-driven phase transformation and to improve the adhesion strength and corrosion resistance, simultaneously. Selection of the appropriate annealing condition, 25...
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Published in | Journal of alloys and compounds Vol. 836; p. 155448 |
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Main Authors | , , , , , , , |
Format | Journal Article |
Language | English |
Published |
Lausanne
Elsevier B.V
25.09.2020
Elsevier BV |
Subjects | |
Online Access | Get full text |
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Summary: | This study reports a “high temperature fast annealing” approach to tailor the microstructure of ZnMg–Zn bilayer coatings through a diffusion-driven phase transformation and to improve the adhesion strength and corrosion resistance, simultaneously. Selection of the appropriate annealing condition, 250 °C for 3 min, promotes the formation of MgZn2 on the topmost surface of the coating and Mg2Zn11 at the interface of ZnMg/Zn. This results to an increase of the adhesion strength from 65 MPa in the as-deposited condition to 82 MPa after annealing as well as a reduction in the corrosion current density from 0.91 to 0.52 μA/cm2, indicating enhanced corrosion resistance. The diffusion of the elements at high temperatures is also modeled to predict the stability region of phases during the annealing treatment. An excellent correlation is obtained between simulation and the experimental results.
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•High temperature fast annealing approach is designed to tailor the microstructure of ZnMg–Zn bilayer coating.•The diffusion-limited growth of intermetallic phases in the ZnMg–Zn bi-layered coatings is simulated.•Adhesion strength and corrosion resistance of the coating are improved simultaneously by annealing. |
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ISSN: | 0925-8388 1873-4669 |
DOI: | 10.1016/j.jallcom.2020.155448 |