XPCS: Nanoscale motion and rheology

• Published in: Current opinion in colloid & interface science Vol. 17; no. 1; pp. 3 - 12
• Main Author: Leheny, Robert L.
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier Ltd 01.02.2012; Elsevier
• Subjects: Block copolymers; Blocking; Chemistry; Colloidal gels; Colloidal gels. Colloidal sols; Colloidal state and disperse state; Colloids; Complex fluids; Exact sciences and technology; Fluid dynamics; gels; General and physical chemistry; Microrheology; Nanocomposites; Nanomaterials; Nanostructure; Phases; Polymer surfaces; Polymer thin films; polymers; rheological properties; Rheology; spectroscopy; Structural dynamics; X-radiation; X-ray photon correlation spectroscopy; Structural dynamics; Polymer surfaces; Microrheology; Rheology; X-ray photon correlation spectroscopy; Polymer thin films; Complex fluids; Block copolymers; Colloidal gels; Motion; Correlation; Fluid; Polymer; X ray; Review; Photon; Thin film; Colloidal gel; Dynamics; Block copolymer
• ISSN: 1359-0294; 1879-0399
• DOI: 10.1016/j.cocis.2011.11.002

X-ray photon correlation spectroscopy (XPCS) has emerged as a powerful technique for investigating slow, nanometer-scale structural dynamics in materials. This paper reviews major directions of recent XPCS research on complex fluids where significant information relevant to their rheological behavior has been obtained. The review focuses on three topics: block-copolymer phases, colloidal glasses and gels, and polymer thin-film surfaces and interfaces. The paper also discusses important anticipated developments for XPCS in the near future and describes some particularly promising directions for the technique in advancing understanding of complex-fluid rheology, including the application of XPCS to microrheology. X-ray photon correlation spectroscopy (XPCS) employs time correlations in the scattering intensity from a coherent x-ray beam to uncover nanometer-scale structural dynamics in materials. This capability has provided unique insight into the microscopic origins of the rheological behavior of complex fluids. [Display omitted] ► XPCS enables investigation of slow, nanometer-scale structural dynamics in materials. ► XPCS has illuminated connections between microscopic dynamics and viscoelasticity in complex fluids. ► Major subjects for XPCS include block copolymers, colloidal glasses and gels, and polymer thin films and interfaces. ► Opportunities with XPCS are expected to grow dramatically in the coming years.