ZnS-Based Photonic Crystals

• Published in: Physica status solidi. B. Basic research Vol. 229; no. 2; pp. 949 - 960
• Main Authors: Park, W., King, J.S., Neff, C.W., Liddell, C., Summers, C.J.
• Format: Journal Article Conference Proceeding
• Language: English
• Published: Berlin WILEY-VCH Verlag Berlin GmbH 01.01.2002; WILEY‐VCH Verlag Berlin GmbH; Wiley
• Subjects: 71.20.Nr; 78.20.Ci; 85.60.Bt; Applied sciences; Condensed matter: electronic structure, electrical, magnetic, and optical properties; Electron density of states and band structure of crystalline solids; Electron states; Electronics; Exact sciences and technology; Optical constants (including refractive index, complex dielectric constant, absorption, reflection and transmission coefficients, emissivity); Optical constants: refractive index, complex dielectric constant, absorption, reflection and transmission coefficients, emissivity; Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation; Optical properties of bulk materials and thin films; Optoelectronic device characterization, design, and modeling; Optoelectronic devices; Physics; S8.11; Semiconductor compounds; Semiconductor electronics. Microelectronics. Optoelectronics. Solid state devices; Two-dimensional systems; Zinc sulfides; Inorganic compounds; Semiconductor materials; II-VI compound; Electron beam lithography; Refractive index; Three-dimensional systems; Transition element compounds; Color; Nanoparticles; Self-assembly; Energy gap; Photonic band; Photonic crystal; Phosphors; Decay time; Infrared radiation; Infiltration; Modelling; Transparent material
• ISSN: 0370-1972; 1521-3951
• DOI: 10.1002/1521-3951(200201)229:2<949::AID-PSSB949>3.0.CO;2-K

Recent studies of the application of II–VI materials to the fabrication of photonic crystals are reported. Modeling studies show the potential of ZnS photonic crystals to provide a new method of controlling the emission characteristics of this material system so as to enhance color, intensity and decay time. The same structures are also shown to possess giant refraction and dispersion properties that can be used to control (collect, focus and steer) light. The fabrication of these period structures is addressed. Two approaches are being considered: the fabrication of two‐dimensional ZnS photonic crystals by conventional electron beam lithography and the formation of three‐dimensional ZnS photonic crystals by cost‐effective self‐assembly methods. ZnS and related II–VI compounds are very attractive for applications in photonic crystal devices operating in the visible and near IR region due to their high indices of refraction and large bandgaps that make them highly transparent in the visible. We report recent studies on the self‐assembly of nanoparticles and subsequent ZnS infiltration techniques that can be used to control the emission and out‐coupling properties of phosphors embedded in a photonic crystal.