Vapor‐Phase Linker Exchange of the Metal–Organic Framework ZIF‐8: A Solvent‐Free Approach to Post‐synthetic Modification

Zeolitic imidazolate frameworks (ZIFs) are a sub‐class of metal–organic frameworks (MOFs). Although generally stable, ZIFs can undergo post‐synthetic linker exchange (PSLE) in solution under mild conditions. Herein, we present a novel, solvent‐free approach to post‐synthetic linker exchange through...

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Published inAngewandte Chemie International Edition Vol. 58; no. 51; pp. 18471 - 18475
Main Authors Marreiros, João, Van Dommelen, Lenz, Fleury, Guillaume, Oliveira‐Silva, Rodrigo, Stassin, Timothée, Iacomi, Paul, Furukawa, Shuhei, Sakellariou, Dimitrios, Llewellyn, Philip L., Roeffaers, Maarten, Ameloot, Rob
Format Journal Article
LanguageEnglish
Published Germany Wiley Subscription Services, Inc 16.12.2019
EditionInternational ed. in English
Subjects
Exchanging
Metal-organic frameworks
Metals
mixed-linker ZIFs
solvent-free modification
Solvents
vapor-phase linker exchange
Vapors
Zeolites
ZIF-8
vapor-phase linker exchange
solvent-free modification
ZIF-8
mixed-linker ZIFs
metal-organic frameworks
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Summary:Zeolitic imidazolate frameworks (ZIFs) are a sub‐class of metal–organic frameworks (MOFs). Although generally stable, ZIFs can undergo post‐synthetic linker exchange (PSLE) in solution under mild conditions. Herein, we present a novel, solvent‐free approach to post‐synthetic linker exchange through exposure to linker vapor. Vaporous materials: Although generally stable, zeolitic imidazolate frameworks (ZIFs) can undergo post‐synthetic linker exchange (PSLE) in solution under mild conditions. A novel, solvent‐free approach to PSLE through exposure to linker vapor is presented.
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ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201912088