A [3]Rotaxane Host Selects Between Stereoisomers

What has it got in its pockets? A new approach to the selective binding and reporting of stereoisomers using mechanical bonding to produce a well‐defined three‐dimensional binding pocket was recently reported by Beer and co‐workers. The highly stereoselective binding of stereoisomers by the reported...

Full description

Saved in:
Bibliographic Details
Published inAngewandte Chemie International Edition Vol. 57; no. 17; pp. 4462 - 4464
Main Authors Denis, Mathieu, Goldup, Stephen Michael
Format Journal Article
LanguageEnglish
Published Germany Wiley Subscription Services, Inc 16.04.2018
EditionInternational ed. in English
Subjects
anions
host–guest systems
rotaxanes
Selective binding
Stereoisomers
stereoselectivity
supramolecular chemistry
Workers
host-guest systems
rotaxanes
stereoselectivity
anions
supramolecular chemistry
Online AccessGet full text

Cover

More Information
Summary:What has it got in its pockets? A new approach to the selective binding and reporting of stereoisomers using mechanical bonding to produce a well‐defined three‐dimensional binding pocket was recently reported by Beer and co‐workers. The highly stereoselective binding of stereoisomers by the reported [3]rotaxane suggest that the use of the mechanical bond to engineer a binding pocket has great potential for the development of stereoselective hosts.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201800665