Preparation of Nano-Apatite Grafted Glass-Fiber-Reinforced Composites for Orthodontic Application: Mechanical and In Vitro Biofilm Analysis

• Published in: Materials Vol. 15; no. 10; p. 3504
• Main Authors: Khan, Abdul Samad, Alshaia, Alaa, AlDubayan, AlAnood, Alarifi, Sundus, Alamri, Abdulaziz, Aldossary, Hanan, Ahmed, Syed Zubairuddin, Ateeq, Ijlal Shahrukh, Hakeem, Abbas Saeed, Rehman, Suriya
• Format: Journal Article
• Language: English
• Published: Switzerland MDPI AG 13.05.2022; MDPI
• Subjects: Adhesion tests; Apatite; Biofilms; Composite materials; Composition; Cyclic loads; Debonding; Enamel; Ethanol; Evaluation; Failure modes; Fiber composites; Fibrous composites; Fourier transforms; glass fibers; Glass-epoxy composites; Grafting; Hydroxyapatite; Hypotheses; Materials; Mechanical properties; Morphology; nano-particles; Optical microscopes; Orthodontic appliances; Orthodontics; Polymerization; Properties; Raman spectroscopy; Resins; retainers; Stainless steels; Static loads; Teeth; Saudi Arabia; St Louis Missouri; United States > US; Germany; hydroxyapatite; glass fibers; orthodontics; fatigue testing; retainers; biofilm; grafting; bond strength; antibacterial; nano-particles
• ISSN: 1996-1944; 1996-1944
• DOI: 10.3390/ma15103504

This study aimed to fabricate nano-hydroxyapatite (nHA) grafted/non-grafted E-glass-fiber-based (nHA/EG) and E-glass fiber (EG) orthodontic retainers and to compare their properties with commercially available retainers. Stainless-steel (SS) retainers and everStick Ortho (EST) were used as control groups. The retainers were evaluated with Raman spectroscopy and bonded to bovine teeth. The samples were fatigued under cyclic loading (120,000 cycles) followed by static load testing. The failure behavior was evaluated under an optical microscope and scanning electron microscope. The strain growth on the orthodontic retainers was assessed (48h and 168h) by an adhesion test using and . The characteristic peaks of resin and glass fibers were observed, and the debonding force results showed a significant difference among all of the groups. SS retainers showed the highest bonding force, whereas nHA/EG retainers showed a non-significant difference from EG and EST retainers. SS retainers' failure mode occurred mainly at the retainer-composite interface, while breakage occurred in glass-fiber-based retainers. The strains' adhesion to EST and EG was reduced with time. However, it was increased with nHA/EG. Fabrication of nHA/EG retainers was successfully achieved and showed better debonding force compared to other glass-fiber-based groups, whereas non-linear behavior was observed for the strains' adhesion.